Photothermal conversion represents one crucial approach for solar energy harvesting and its exploitation as a sustainable alternative to fossil fuels; however, an efficient, cost-effective, and generalized approach to enhance the photothermal conversion processes is still missing. Herein, we develop a feasible and efficient photothermal conversion strategy that achieves simultaneous light and heat management using supported metal clusters and WSe interlayer toward enhanced CO hydrogenation photothermal catalysis. The interlayer can simultaneously reduce heat loss in the catalytic layer and improve light absorption, leading to an 8-fold higher CO conversion rate than the controls.
View Article and Find Full Text PDFIn this study, Pt(0) microscrolls are synthesized on polished Ni galvanic replacement reaction (GRR). Employing optical microscopy, the dynamic motion of the catalytic microscrolls as micromotors in HO solutions is revealed. This method offers a rapid fabrication of scrolls from diverse noble metals and alloys.
View Article and Find Full Text PDFPhotothermal catalytic CO hydrogenation holds great promise for relieving the global environment and energy crises. The "nano-greenhouse effect" has been recognized as a crucial strategy for improving the heat management capabilities of a photothermal catalyst by ameliorating the convective and radiative heat losses. Yet it remains unclear to what degree the respective heat transfer and mass transport efficiencies depend on the specific structures.
View Article and Find Full Text PDFInteraction of the solution droplet surface with gaseous components of the environment can lead to the formation of highly ordered patterns, such as dendrites. Here, we show that these structures can be spontaneously created during the open-air interaction of aqueous solution drop of titanium(III) salt with gaseous NH at the contact boundary thereof. The conditions have been identified under which radially ordered dendritic patterns can form on the surface of the TiCl solution droplet.
View Article and Find Full Text PDFThis article discusses the features of the synthesis and application of porous two-dimensional nanomaterials in developing conductometric gas sensors based on metal oxides. It is concluded that using porous 2D nanomaterials and 3D structures based on them is a promising approach to improving the parameters of gas sensors, such as sensitivity and the rate of response. The limitations that may arise when using 2D structures in gas sensors intended for the sensor market are considered.
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