Thermomechanical properties of confined magnetic nanoparticles in electrospun polyacrylonitrile nanofiber matrix exposed to a magnetic environment: structure, morphology, and stabilization (cyclization).

Electrospun metal oxide-polymer nanofiber composites hold promise for revolutionizing biomedical applications due to their unique combination of electronic and material properties and tailorable functionalities. An investigation into the incorporation of Fe-based nanofillers for optimizing the polyacrylonitrile matrix was conducted, where the systematic and organized arrangement of inorganic components was achieved through non-covalent bonding. These carefully dispersed nanomaterials exhibit the intrinsic electronic characteristics of the polymers and concurrently respond to external magnetic fields.

Strong influence of magnetic field and non-uniform stress on elastic modulus and transition temperatures of twinned Ni-Fe(Co)-Ga alloy.

The magnetization value and electric resistivity of the single-crystalline sample of NiFeCoGa shape memory alloy were measured. The elastic modulus was determined by the Dynamic Mechanical Analysis (DMA). The characteristic temperatures of martensitic transformation (MT) of the alloy were estimated from the temperature dependences of magnetization, electric resistivity and elastic modulus.

Antibacterial activity, cytocompatibility, and thermomechanical stability of TiZrCuPd bulk metallic glass.

This paper envisions TiZrCuPd bulk metallic glass as an oral implant material and evaluates its antibacterial performance in the inhabitation of oral biofilm formation in comparison with the gold standard Ti-6Al-4V implant material. Metallic glasses are superior in terms of biocorrosion and have a reduced stress shielding effect compared with their crystalline counterparts. Dynamic mechanical and thermal expansion analyses on TiZrCuPd show that these materials can be thermomechanically shaped into implants.

Structure-dynamics relationships in cryogenically deformed bulk metallic glass.

The atomistic mechanisms occurring during the processes of aging and rejuvenation in glassy materials involve very small structural rearrangements that are extremely difficult to capture experimentally. Here we use in-situ X-ray diffraction to investigate the structural rearrangements during annealing from 77 K up to the crystallization temperature in CuZrAlHfCo bulk metallic glass rejuvenated by high pressure torsion performed at cryogenic temperatures and at room temperature. Using a measure of the configurational entropy calculated from the X-ray pair correlation function, the structural footprint of the deformation-induced rejuvenation in bulk metallic glass is revealed.

Water in Mesoporous Confinement: Glass-To-Liquid Transition or Freezing of Molecular Reorientation Dynamics?

The first mechanical relaxation measurements (f = 400 Hz) of water confined in micro-porous silica were performed more than 40 years ago. The authors reported a so called "capillary transition" (here denoted as P3) of water in the core of the pores and a second one at a lower temperature, which they called the "adsorbate transition" (P1 in present work) related to water near the surface of the pores. The capillary transition was identified with the freezing of water in the centre of the pores.