Spectrochim Acta A Mol Biomol Spectrosc
February 2025
This work reports the synthesis of hydroxyapatite (HAp) nanoparticles co-doped with trivalent terbium (Tb) and samarium (Sm) ions by a surfactant free chemical precipitation method. Co-doping enables to combine the optical properties of Tb and Sm ions. Characterization techniques like X-Ray diffraction (XRD), transmission electron microscopy (TEM), Fourier transform infrared (FTIR) spectroscopy, inductively coupled plasma-optical emission spectroscopy (ICP-OES), energy dispersive X-ray spectroscopy (EDX) were used to determine the crystalline and structural properties.
View Article and Find Full Text PDFLuminescence
May 2022
Spectrochim Acta A Mol Biomol Spectrosc
May 2022
Linear and nonlinear optical properties of near-infrared laser grade dye LDS 821 in different solvents and Salmon Deoxyribonucleic acid (DNA) were studied using spectroscopic and Z-scan techniques. UV-Vis absorption spectrum of the dye shows a bathochromic shift with a decrease in the solvent polarity parameter, and in DNA, the dye exhibits a hypochromic shift. The fluorescence spectrum of the dye does not show any notable correlation with the solvent polarity parameter, but in DNA, the fluorescence intensity of the dye decreases with the incremental addition of DNA.
View Article and Find Full Text PDFWe report the structural engineering of ZnO nanostructures by a consistent solution method using distinct solvents such as ethylene glycol, 1-butanol, acetic acid and water. The growth kinetics are found to depend strongly on the physicochemical properties of the solvent and zeta potential of the colloidal solution. Furthermore, the resulting nanostructures as a photoanode material, displayed a prominent structure dependent property in determining the efficiency of dye-sensitized solar cells (DSSCs).
View Article and Find Full Text PDFWe report a commercially available benzothiazolium based dye LDS 821 (Styryl 9M) as a near infrared fluorescent probe for the detection of lysozyme amyloid fibrils. Change in the photophysical properties of the dye with respect to the change in viscosity of the environment is investigated. Increment in fluorescence lifetime and quantum yield with increment in viscosity proves the dye as a molecular rotor.
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