Evolution of the Microrobots: Stimuli-Responsive Materials and Additive Manufacturing Technologies Turn Small Structures into Microscale Robots.

The development of functional microsystems and microrobots that have characterized the last decade is the result of a synergistic and effective interaction between the progress of fabrication techniques and the increased availability of smart and responsive materials to be employed in the latter. Functional structures on the microscale have been relevant for a vast plethora of technologies that find application in different sectors including automotive, sensing devices, and consumer electronics, but are now also entering medical clinics. Working on or inside the human body requires increasing complexity and functionality on an ever-smaller scale, which is becoming possible as a result of emerging technology and smart materials over the past decades.

Preparation of different conjugated polymers characterized by complementary electronic properties from an identical precursor.

The possibility of generating regions with different electronic properties within the same organic semiconductor thin film could offer novel opportunities for designing and fabricating organic electronic devices and circuits. This study introduces a new approach based on a novel type of highly processable polymer precursor that can yield two different conjugated polymers characterized by complementary electronic properties, promoting electron or hole transport, from the same starting material. In particular, these multipotent precursors comprise functionalized dihydroanthracene units that can offer several functionalization opportunities to improve the solubility or insert specific functionalities.

Biomedical applications of engineered heparin-based materials.

Heparin is a negatively charged polysaccharide with various chain lengths and a hydrophilic backbone. Due to its fascinating chemical and physical properties, nontoxicity, biocompatibility, and biodegradability, heparin has been extensively used in different fields of medicine, such as cardiovascular and hematology. This review highlights recent and future advancements in designing materials based on heparin for various biomedical applications.

Polyketone-Based Anion-Exchange Membranes for Alkaline Water Electrolysis.

Anion-exchange membranes (AEMs) are involved in a wide range of applications, including fuel cells and water electrolysis. A straightforward method for the preparation of efficient AEMs consists of polymer functionalization with robust anion-exchange sites. In this work, an aliphatic polyketone was functionalized with 1-(3-aminopropyl)imidazole through the Paal-Knorr reaction, with a carbonyl (C %) conversion of 33%.