Mechanochemical Reactivity of a 1,2,4-Triazoline-3,5-dione-Anthracene Diels-Alder Adduct.

Force-responsive molecules that produce fluorescent moieties under stress provide a means for stress-sensing and material damage assessment. In this work, we report a mechanophore based on Diels-Alder adduct TAD-An of 4,4'-(4,4'-diphenylmethylene)-bis-(1,2,4-triazoline-3,5-dione) and initiator-substituted anthracene that can undergo retro-Diels-Alder (rDA) reaction by pulsed ultrasonication and compressive activation in bulk materials. The influence of having C-N versus C-C bonds at the sites of bond scission is elucidated by comparing the relative mechanical strength of TAD-An to another Diels-Alder adduct MAL-An obtained from maleimide and anthracene.

Antifouling Properties of Amine-Oxide-Containing Zwitterionic Polymers.

Biofouling due to nonspecific proteins or cells on the material surfaces is a major challenge in a range of applications such as biosensors, medical devices, and implants. Even though poly(ethylene glycol) (PEG) has become the most widely used stealth material in medical and pharmaceutical products, the number of reported cases of PEG-triggered rare allergic responses continues to increase in the past decades. Herein, a new type of antifouling material poly(amine oxide) (PAO) has been evaluated as an alternative to overcome nonspecific foulant adsorption and impart comparable biocompatibility.

Utilizing waste corn-cob in biosynthesis of noble metallic nanoparticles for antibacterial effect and catalytic degradation of contaminants.

In the present study, cost-effective, and environmentally friendly fabrication of silver and gold nanoparticles was performed by using aqueous extract of waste corn-cob. The formation of the metallic nanoparticles (MNPs) was optimized by UV-Vis method. The phytoconstituents were responsible for reduction of silver and gold ions to silver nanoparticles (CC-AgNPs) and gold nanoparticles (CC-AuNPs) which were demonstrated by Fourier-transform infrared (FTIR) spectroscopy while formation of AgCl was attributed to the presence of chloride ions in the aqueous extract.

Energy saving for OpenFlow switch on the NetFPGA platform based on queue engineering.

Data centers play an important role in our daily activities. The increasing demand on data centers in both scale and size has led to huge energy consumption that rises the cost of data centers. Besides, environmental impacts also increase considerably due to a large amount of carbon emissions.

Therapeutic approach in managing patients with large vestibular aqueduct syndrome (LVAS).

Objective: To discuss the clinical approach in managing patients with large vestibular aqueduct syndrome.

Methods: Over the period from November 1997 to March 2005, 106 children have been fitted with cochlear implants in Antwerp University Hospital (UZA). The Hospital University of Maastricht (azM) had implanted 36 children since 1999 to March 2005.