Activation of carbon disulfide by a hypersilyl germylene.

In this work, the insertion of CS into the Ge-Si bond of PhC(NBu)Ge-Si(SiMe) (1) has been investigated, resulting in the formation of PhC(NBu)Ge-C(S)-S-Si(SiMe) (2). Interestingly, the addition of NHC to 2 allows the release of NHC·CS with concomitant regeneration of 1. Addition of another equivalent of 1 or an analogous hypersilyl silylene, [PhC(NBu)Si-Si(SiMe)], to 2 led to the formation of compounds with a GeS (3) or a SiS (4) bond.

Deciphering Bisphenol A degradation by Coelastrella sp. M60: unravelling metabolic insights through metabolomics analysis.

Microalgae, owing to their efficacy and eco-friendliness, have emerged as a promising solution for mitigating the toxicity of Bisphenol A (BPA), a hazardous environmental pollutant. This current study was focused on the degradation of BPA by Coelastrella sp. M60 at various concentrations (10-50 mg/L).

CD44 tagged hyaluronic acid - chitosan liposome carrier for the delivery of berberine and doxorubicin into lung cancer cells.

Liposomes are unique biomolecular, capable of loading both hydrophilic and hydrophobic molecules and delivered into the biological system. Liposomes (L) coated with hyaluronic acid (HA) and chitosan (CS) carrier system was fabricated. Berberine (BER) and doxorubicin (DOX) were encapsulated to enhance drug proliferation and therapeutic effect in lung cancer cells.

infections with varied presentations and different antimicrobial susceptibility - A case series.

We report three sporadic infections by from Government Medical College Kozhikode in Kerala state, South India over a period of three years. Two cases were commenced in the community in immunocompromised children beyond the newborn period, but both recovered promptly. Another was a hospital-acquired meningitis in a newborn baby who developed neurologic sequelae.