Publications by authors named "V K Tzitzios"

Αfter the impressive evolution of graphene and its derivatives, a large number of two dimensional (2D) materials with important optical and electrical properties have been successfully fabricated. Liquid phase exfoliation (LPE) of layered and non-layered materials has become a widely applied method for the preparation of 2D nanostructures with an extensive variety of applications. However, in most cases organic solvents are used as liquid phase which are often toxic and environmentally unfriendly and lead to low yields.

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CuFeS is a prominent chalcogenide that possesses similar optical properties and a significantly lower cost, compared to gold. Additionally, covalent organic frameworks are a class of materials at the forefront of current research, mainly used as photoactive components and porous absorbers. Hence, in this work, hydrophilic CuFeS particles are coupled with multi-functional covalent organic frameworks through ionic bonding to produce a hybrid material with unique and optimized properties.

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Bimetallic colloidal CoPt nanoalloys with low platinum content were successfully synthesized following a modified polyol approach. Powder X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA), and transmission electron microscopy (TEM) studies were performed to estimate the crystal structure, morphology, and surface functionalization of the colloids, respectively, while the room-temperature magnetic properties were measured using a vibrating sample magnetometer (VSM). The particles exhibit excellent uniformity, with a narrow size distribution, and display strong room-temperature hysteretic ferromagnetic behavior even in the as-made form.

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Two-dimensional (2D) metal borides are a class of ceramic materials with diverse structural and topological properties. These diverse material properties of metal borides are what forms the basis of their interdisciplinarity and their applicability in various research fields. In this study, we highlight which fundamental and practical parameters need to be taken into consideration when designing nanomaterials for specific applications.

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Magnetic FeO nanoparticles "decorated" by LAPONITE® nanodisks have been materialized utilizing the Schikorr reaction following a facile approach and tested as mediators of heat for localized magnetic hyperthermia (MH) and as magnetic resonance imaging (MRI) agents. The synthetic protocol involves the interaction between two layered inorganic compounds, ferrous hydroxide, Fe(OH), and the synthetic smectite LAPONITE® clay Na[(SiMgLi)O(OH)], towards the formation of superparamagnetic FeO nanoparticles, which are well decorated by the diamagnetic clay nanodisks. The latter imparts high negative -potential values (up to -34.

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