J Phys Chem B
October 2023
We discuss the triangle of the liquid-gas concept within the fluid-lattice gas isomorphism approach and the Zeno-element, taking the hard-core Yukawa fluid (HCAYF) as an example. The applicability of such an isomorphism is demonstrated by the symmetrization of binodals with mapping onto the Ising model coexistence curve. We show that the parameters of the isomorphism transformation reflect the liquid-phase instability for hard-core Yukawa potential and its generalization.
View Article and Find Full Text PDFIn this work, we study the global isomorphism between the liquid-vapor equilibrium of the hardcore attractive Yukawa fluid (HCAYF) and that of the Lattice Gas (LG) model of the Ising-like type. The applicability of the global isomorphism transformation and the dependence of its parameters on the screening length of the Yukawa potential are discussed. These parameters determine both the slope of the rectilinear diameter of the liquid-vapor binodal and the Zeno-element, which are the core ingredients of the fluid-LG isomorphism.
View Article and Find Full Text PDFWe show how to obtain the critical compressibility factor Z(c) for simple and associative Lennard-Jones fluids using the critical characteristics of the Ising model on different lattices. The results show that low values of critical compressibility factor are correlated with the associative properties of fluids in critical region and can be obtained on the basis of the results for the Ising model on lattices with more than one atom per cell. An explanation for the results on the critical point line of the Lennard-Jones fluids and liquid metals is proposed within the global isomorphism approach.
View Article and Find Full Text PDFJ Chem Phys
November 2013
The relation between the critical compressibility factors Zc of the Lennard-Jones fluid and the Lattice Gas (Ising model) is derived within the global isomorphism approach. On this basis, we obtain the alternative form for the value of the critical compressibility factor which is different from widely used phenomenological Timmermans relation. The estimates for the critical pressure Pc and Zc of the Lennard-Jones fluid are obtained in case of two and three dimensions.
View Article and Find Full Text PDFInfluence of alpha-lipoic acid (LA) on liver glutathione system of Ehrlich ascites carcinoma (EAC) transplanted mice was studied. LA causes multidirectional influence on glutathione system of healthy mice. EAC transforms LA influence, strengthening prooxidative effects more expressed at introduction in early terms after inoculation of the tumor.
View Article and Find Full Text PDF