Publications by authors named "V I Kasyanenko"

Atomic force microscopy, infrared spectroscopy and NMR studied morphological and physicochemical properties of calcium hydroxyapatite powders produced by changing the temperature parameters of synthesis. Features of morphology formation of calcium hydroxyapatite nanoparticles with an annealing temperature within 200°C to 1,100°C were determined. It is shown that the particle size of the apatite obtained that annealed 700°C is 40 nm corresponding to the particle size of apatite in native bone.

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We performed a complex morphoimmunohistochemical study of synchronous bilateral breast cancer (diagnosed in 0.69% cases in women of the postproductive period after the age of 50). The molecular genetic characteristics of this cancer were detected and the algorithm of diagnostic studies was suggested.

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The effect of honey and pollen for an experimental gastric ulcer in rats by electromyography was investigated Okabe ulcer by applying the 100% acetic acid in the gastric serosa was simulated. Honey and pollen prevent the development of painful gastric motility, which confirms its gastroprotective action.

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Article Synopsis
  • The study aimed to understand how energy and vibrational relaxation occur in polyatomic molecules due to anharmonicity.
  • A generalized version of Marcus electron transfer theory was used to model the energy transport dynamics, along with improvements to existing theoretical frameworks.
  • The approach was successfully applied to several molecules, showing that the theoretical results aligned well with experimental findings from relaxation-assisted two-dimensional infrared spectroscopy.
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High-frequency vibrational modes in molecules in solution are sensitive to temperature and shift either to lower or higher frequencies with the temperature increase. These frequency shifts are often attributed to specific interactions of the molecule and to the solvent polarization effect. We found that a substantial and often dominant contribution to sensitivity of vibrational high-frequency modes to temperature originates from anharmonic interactions with other modes in the molecule.

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