Aquatic Ecosystem Risk Assessment Generated by Accidental Silver Nanoparticle Spills in Groundwater.

This paper aims to create a new model for assessing the ecosystem risk in rivers and wetlands that are linked to accidental spills of silver nanoparticles (AgNPs) in soil/groundwater. Due to the uncertainty of the modeling inputs, a combination of two well-known risk assessment methodologies (Monte Carlo and fuzzy logic) were used. To test the new model, two hypothetical, accidental AgNP soil spill case studies were evaluated; both of which were located at the end of the Llobregat River basin within the metropolitan area of Barcelona (NE Spain).

Functionalization of Screen-Printed Electrodes with Grape Stalk Waste Extract-Assisted Synthesized Silver and Gold Nanoparticles: Perspectives of Electrocatalytically Enhanced Determination of Uranyl Ion and Other Heavy Metals Ions.

Recently, nanotechnology and nanoparticles (NPs) such as AgNPs and AuNPs have become important in analytical chemistry due to their great potential to improve the performance of electrochemical sensors. In this work, Ag and Au nanoparticles have been synthesized using a green route in which a grape stalk waste extract is used as a reducing agent to obtain metallic nanoparticles. These NPs were used to customize the surface of commercial screen-printed electrodes (SPCNFEs).

Synthesis of Polymer Precursor 12-Oxododecenoic Acid Utilizing Recombinant Papaya Hydroperoxide Lyase in an Enzyme Cascade.

Hydroperoxide lyases (HPLs) catalyze the splitting of 13S-hydroperoxyoctadecadienoic acid (13S-HPODE) into the green note flavor hexanal and 12-oxo-9(Z)-dodecenoic acid, which is not yet used industrially. Here, HPL from Carica papaya (HPL) was cloned and functionally expressed in Escherichia coli to investigate synthesis of 12-oxo-9(Z)-dodecenoic acid in detail. To improve the low catalytic activity of full-length HPL, the hydrophobic, non-conserved N-terminal sequence was deleted.