Combining batch experiments and spectroscopy for realistic surface complexation modelling of the sorption of americium, curium, and europium onto muscovite.

For a safe enclosure of contaminants, for instance in deep geological repositories of radioactive waste, any processes retarding metal migration are of paramount importance. This study focusses on the sorption of trivalent actinides (Am, Cm) and lanthanides (Eu) to the surface of muscovite, a mica and main component of most crystalline rocks (granites, granodiorites). Batch sorption experiments quantified the retention regarding parameters like pH (varied between 3 and 9), metal concentration (from 0.

Exploring the Reduction Mechanism of Tc(VII) in NaClO: A Spectro-Electrochemical Approach.

Technetium (Tc) is an environmentally relevant radioactive contaminant whose migration is limited when Tc(VII) is reduced to Tc(IV). However, its reaction mechanisms are not well understood yet. We have combined electrochemistry, spectroscopy, and microscopy (cyclic voltammetry, rotating disk electrode, X-ray photoelectron spectroscopy, and Raman and scanning electron microscopy) to study Tc(VII) reduction in non-complexing media: 0.

Community Data Mining Approach for Surface Complexation Database Development.

This paper presents a comprehensive data-to-model workflow, including a findable, accessible, interoperable, reusable (FAIR) community sorption database (newly developed LLNL Surface Complexation/Ion Exchange (L-SCIE) database) along with a data fitting workflow to efficiently optimize surface complexation reaction constants with multiple surface complexation model (SCM) constructs. This workflow serves as a universal framework to mine, compile, and analyze large numbers of published sorption data as well as to estimate reaction constants for parameterizing reactive transport models. The framework includes (1) data digitization from published papers, (2) data unification including unit conversions, and (3) data-model integration and reaction constant estimation using geochemical software PHREEQC coupled with the universal parameter estimation code PEST.

New insights into U(VI) sorption onto montmorillonite from batch sorption and spectroscopic studies at increased ionic strength.

The influence of ionic strength up to 3 mol kg (background electrolytes NaCl or CaCl) on U(VI) sorption onto montmorillonite was investigated as function of pH in absence and presence of CO. A multi-method approach combined batch sorption experiments with spectroscopic methods (time-resolved laser-induced fluorescence spectroscopy (TRLFS) and in situ attenuated total reflection Fourier-transform infrared spectroscopy (ATR FT-IR)). In the absence of atmospheric carbonate, U(VI) sorption was nearly 99% above pH 6 in both NaCl and CaCl and no significant effect of ionic strength was found.

Reductive immobilization of Tc(VII) by FeS: The effect of marcasite.

Reductive immobilization of Tc by a synthetic FeS mixture, i.e. marcasite-pyrite 60:40, was studied by a combined approach of batch experiments and powder X-ray diffraction, X-ray photoelectron spectroscopy as well as Raman microscopy.