A homonuclear molecule with a permanent electric dipole moment.

Permanent electric dipole moments in molecules require a breaking of parity symmetry. Conventionally, this symmetry breaking relies on the presence of heteronuclear constituents. We report the observation of a permanent electric dipole moment in a homonuclear molecule in which the binding is based on asymmetric electronic excitation between the atoms.

Rydberg trimers and excited dimers bound by internal quantum reflection.

In a combined experimental and theoretical effort we report on two novel types of ultracold long-range Rydberg molecules. First, we demonstrate the creation of triatomic molecules of one Rydberg atom and two ground-state atoms in a single-step photoassociation. Second, we assign a series of excited dimer states that are bound by a so far unexplored mechanism based on internal quantum reflection at a steep potential drop.

Observation of ultralong-range Rydberg molecules.

Rydberg atoms have an electron in a state with a very high principal quantum number, and as a result can exhibit unusually long-range interactions. One example is the bonding of two such atoms by multipole forces to form Rydberg-Rydberg molecules with very large internuclear distances. Notably, bonding interactions can also arise from the low-energy scattering of a Rydberg electron with negative scattering length from a ground-state atom.

Rydberg excitation of Bose-Einstein condensates.

Rydberg atoms provide a wide range of possibilities to tailor interactions in a quantum gas. Here, we report on Rydberg excitation of Bose-Einstein condensed 87Rb atoms. The Rydberg fraction was investigated for various excitation times and temperatures above and below the condensation temperature.

Echo experiments in a strongly interacting Rydberg gas.

When ground state atoms are excited to a Rydberg state, van der Waals interactions among them can lead to a strong suppression of the excitation. Despite the strong interactions the evolution can still be reversed by a simple phase shift in the excitation laser field. We experimentally prove the coherence of the excitation in the strong blockade regime by applying an "optical rotary echo" technique to a sample of magnetically trapped ultracold atoms, analogous to a method known from nuclear magnetic resonance.