One-dimensional dissolution of a layered compound in a nonpolar organic solvent is reported for the first time. A high-aspect ratio fluorohectorite modified with a cationic surfactant (dioctadecyldimethylammonium) showed spontaneous delamination into monolayer nanosheets in chloroform.
View Article and Find Full Text PDF2D transition metal carbides and nitrides (MXenes) suggest an uncommonly broad combination of important functionalities amongst 2D materials. Nevertheless, MXene suffers from facile oxidation and colloidal instability upon conventional water-based processing, thus limiting applicability. By experiments and theory, It is suggested that for stability and dispersibility, it is critical to select uncommonly high permittivity solvents such as N-methylformamide (NMF) and formamide (FA) (ε = 171, 109), unlike the classical solvents characterized by high dipole moment and polarity index.
View Article and Find Full Text PDFMetamaterials possess exotic properties that do not occur in nature and have attracted significant attention in research and engineering. Two decades ago, the field of metamaterials emerged from linear electromagnetism, and today it encompasses a wide range of aspects related to solid matter, including electromagnetic and optical, mechanical and acoustic, as well as unusual thermal or mass transport phenomena. Combining different material properties can lead to emergent synergistic functions applicable in everyday life.
View Article and Find Full Text PDFThe effect of tempforming on the strength and fracture toughness of 0.4%C-2%Si-1%Cr-1%Mo-VNb steel was examined. Plate rolling followed by tempering at the same temperature of 600 °C increases yield stress by 25% and the Charpy V-notch impact energy by a factor of ~10.
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