Temporal variability in nutrient concentrations and loads in the River Tamar and its catchment (SW England) between 1974 and 2004.

This study reports the results from the analyses of a 30-year (1974-2004) river water quality monitoring dataset for NO x -N (NO₃-N + NO2-N), NH₄-N, PO₄-P and SiO₂-Si at the tidal limit of the River Tamar (SW England), an agriculturally dominated and sparsely populated catchment. Annual mean concentrations of NH4-N, PO₄-P and SiO₂-Si were similar to other rural UK rivers, while annual mean concentrations of NO x -N were clearly lower. Estimated values for the 1940s were much lower than for those of post-1974, at least for NO₃-N and PO₄-P.

Sampling, sample treatment and quality assurance issues for the determination of phosphorus species in natural waters and soils.

Phosphorus is an important macronutrient and the accurate determination of phosphorus species in environmental matrices such as natural waters and soils is essential for understanding the biogeochemical cycling of the element, studying its role in ecosystem health and monitoring compliance with legislation. This paper provides a critical review of sample collection, storage and treatment procedures for the determination of phosphorus species in environmental matrices. Issues such as phosphorus speciation, the molybdenum blue method, digestion procedures for organic phosphorus species, choice of model compounds for analytical studies, quality assurance and the availability of environmental CRMs for phosphate are also discussed in detail.