Polyol-Intermediated Facile Synthesis of B-Site-Rich Ru-Based Nanocatalysts for CO-Free Hydrogen Production via Ammonia Decomposition.

Herein, a B-site-rich Ru/MgAlO nanocatalyst for the production of CO-free hydrogen from ammonia (NH) is synthesized using the polyol method. The polyol method enables size-sensitive Ru-nanoparticle growth and controlled B-site formation on the catalyst by tuning the carbon-chain length of the polyol solvent used, obviating the use of a separate stabilizer and enhancing electron donation from Ru (with a high surface electron density) and π-back bonding. The Ru/MgAlO (BG) catalyst synthesized using butylene glycol (a long-carbon-chain solvent) contains 2.

High sulfur content polymer nanoparticles obtained from interfacial polymerization of sodium polysulfide and 1,2,3-trichloropropane in water.

Sulfur-rich materials have recently attracted keen interest for their potentials in optical, electrochemical, and pesticidal applications as well as their utility in dynamic covalent bond chemistry. Many sulfur-rich polymers, however, are insoluble and processing methods are therefore very limited. The synthesis and characterization of water-dispersible polymer nanoparticles (NPs) with the sulfur content exceeding 75% by weight, obtained from the interfacial polymerization between 1,2,3-trichloropropane and sodium polysulfide in water is reported here.