Nitrogen-Rich Barium-Organic Framework for Capture and Cocatalysts Free Chemical Fixation of CO via Cyclic Carbonates and Oxazolidinones.

The carbon dioxide (CO) capture and utilization strategy has emerged as an innovative and multifaceted approach to counteract carbon emissions. In this study, a highly porous muffin polyhedral barium (Ba) ̵ organic framework (BaTATB; HTATB = 4,4',4″--triazine-2,4,6-triyl-tribenzoic acid) was synthesized solvothermally. The three-dimensional honeycomb pore architectures were densely populated with Lewis acidic Ba(II) metal sites and basic nitrogen-rich triazines.

Chemical fractionation and mobility of Cd, Mn, Ni, and Pb in farmland soils near a ceramics company.

Soil contamination due to industrial activity in ceramics production is of concern because of the risk of heavy metal pollution. Successive extraction was used to measure and identify the concentrations of Cd, Mn, Ni, and Pb in farming soils near a ceramics company in Nigeria. Furthermore, soil pH and particle size analyses were determined.

Status of vancomycin-resistant Enterococcus in species of wild birds: A systematic review and meta-analysis.

Wild birds could be a reservoir of medically relevant microorganisms, particularly multidrug-resistant Enterococcus spp. Resistant bacteria's epidemiology and transmission between animals and humans has grown, and their zoonotic potential cannot be ignored. This is the first study to evaluate the status of vancomycin resistant enterococci (VRE) in various wild bird species using meta-analysis and a systematic review.

Parent and Physician Preference for Anxiolytic Medication Prior to Laceration Repair in Young Children.

Objectives Pediatric laceration repair is a daunting process for parents and physicians. The repair could take place quickly if the child is calm and relaxed.This study aimeds to evaluate parental and physician preference for anxiolytic medication administration prior to laceration repair, with a pre-and post-repair survey on parents' and physicians' initial preference and follow-up perception.

Polymeric Materials as Potential Inhibitors Against SARS-CoV-2.

Recently discovered SARS-CoV-2 caused a pandemic that triggered researchers worldwide to focus their research on all aspects of this new peril to humanity. However, in the absence of specific therapeutic intervention, some preventive strategies and supportive treatment minimize the viral transmission as studied by some factors such as basic reproduction number, case fatality rate, and incubation period in the epidemiology of viral diseases. This review briefly discusses coronaviruses' life cycle of SARS-CoV-2 in a human host cell and preventive strategies at some selected source of infection.

Preparation of pH-Indicative and Flame-Retardant Nanocomposite Films for Smart Packaging Applications.

There is an increasing demand for sustainable and safe packaging technologies to improve consumer satisfaction, reduce food loss during storage and transportation, and track the quality status of food throughout its distribution. This study reports the fabrication of colorimetric pH-indicative and flame-retardant nanocomposite films (NCFs) based on polyvinyl alcohol (PVA) and nanoclays for smart and safe food packaging applications. Tough, flexible, and transparent NCFs were obtained using 15% nanoclay loading (PVA-15) with superior properties, including low solubility/swelling in water and high thermal stability with flame-retardant behavior.

Isolation and characterization of microcrystalline cellulose from date seeds (Phoenix dactylifera L.).

This article reports the isolation and characterization of microcrystalline cellulose from date seeds of the date palm tree. The raw ground date seeds (RG-DS) are composed of cellulose matrix wrapped by lignin and hemicellulose as amorphous components. Cellulose was isolated from RG-DS through the following sequence: dewaxing, delignification/(bleaching) and acid hydrolysis.

Polymeric Materials for Conversion of Electromagnetic Waves from the Sun to Electric Power.

Solar photoelectric energy converted into electricity requires large surface areas with incident light and flexible materials to capture these light emissions. Currently, sunlight rays are converted to electrical energy using silicon polymeric material with efficiency up to 22%. The majority of the energy is lost during conversion due to an energy gap between sunlight photons and polymer energy transformation.

Prevalence, risk factors, and antimalarial resistance patterns of falciparum plasmodiasis among pregnant women in Kaduna metropolis, Nigeria.

Objective: Pregnant women infected with malaria represent a significant obstetric problem, especially in the face of antimalarial resistance. This cross-sectional study investigated the prevalence of malaria parasitemia, associated risk factors as well as the antimalarial resistance pattern of isolates from pregnant women attending four selected secondary health facilities in Kaduna State, Nigeria.

Materials And Methods: Blood samples were collected from 353 pregnant women attending selected hospitals.

A Flexible Optical pH Sensor Based on Polysulfone Membranes Coated with pH-Responsive Polyaniline Nanofibers.

A new optical pH sensor based on polysulfone (PSU) and polyaniline (PANI) was developed. A transparent and flexible PSU membrane was employed as a support. The electrically conductive and pH-responsive PANI was deposited onto the membrane surface by in situ chemical oxidative polymerization (COP).

Density functional theory calculations of the internal rotations and vibrational spectra of 2-, 3- and 4-formyl pyridine.

The torsional potentials, molecular conformations and vibrational spectra, of 2-, 3- and 4-formyl pyridine have been investigated using density functional theory (DFT) method with 6-31+G* basis set. From the calculations, 2-formyl pyridine and 3-formyl pyridine were predicted to exist predominantly in cis conformation with the cis-trans rotational barrier of 9.38 kcal/mol and 8.

Ab initio and DFT studies of the molecular structures and vibrational spectra of succinonitrile.

The Molecular structure, conformational stability and vibrational frequencies of succinonitrile NCCH2CH2CN have been investigated with ab initio and density functional theory (DFT) methods implementing the standard 6-311++G* basis set. The potential energy surfaces (PES) have been explored at DFT-B3LYP, HF and MP2 levels of theory. In agreements with previous experimental results, the molecule was predicted to exist in equilibrium mixture of trans and gauche conforms with the trans form being slightly lower in energy.

Theoretical investigation of the structure and vibrational spectra of carbamoyl azide.

Molecular structure and vibrational frequencies of carbamoyl azide NH2CO-NNN have been investigated with ab initio and density functional theory (DFT) methods. The molecular geometries for all the possible conformers of the molecule were optimized using DFT-B3LYP, DFT-BLYP and MP2 applying the standard 6-311++G** basis set. From the calculations, the molecule was predicted to exist predominantly in cis conformation with the cis-trans rotational barrier of about 7.