Erosion behavior of Al-SiC and Al-WC MMCs via powder metallurgy under solid particle impingement.

This study investigates the erosion behavior of Al-SiC and Al-WC metal-based composites in a solid particle impingement environment developed through powder metallurgy. Micro-sized powders of SiC and WC were utilized in different weight proportions (0-10 wt%) for fabricating the composite samples. The angle of impingements of 30-90° and impact velocity of 30-90 m/s were used for solid particle erosion testing.

Development and life cycle assessment (LCA) of super-oleophobic (under water) and super-hydrophilic (in-air) mesh membrane for oily water treatment.

This paper reports the fabrication, characterization, and environmental impact analysis of a super-oleophobic (under water) and super-hydrophilic mesh membrane for oily water treatment. In order to prepare mesh membrane, Titania nanoparticles (NPs) were spray coated on mesh stainless steel followed by calcination at 500 °C. After that, the Titania-coated mesh membrane was characterized using contact angle goniometry (CA), XRD, FE-SEM, EDX and elemental mapping.

Single stage cricoid split laryngoplasty with costochondral rib grafting is a novel approach to treat subglottic stenosis in a paediatric patient: A case report.

Introduction And Importance: Subglottic stenosis (SGS) appears to be a commonly encountered condition in the paediatric age group. Single stage cricoid split laryngoplasty with costochondral rib grafting in paediatric patients is a unique, innovative, and advanced operation in nature. Morbidity and mortality rates can be minimized with early diagnosis and prompt treatment.

Fabrication of Tailored Membranes with Special Surface Wettability Features for Highly Efficient Crude Oil-in-Water Emulsion Separation.

Treating oily wastewater streams such as produced water has a huge potential to resolve the issue of wastewater disposal and generate useful water for reuse. Among different techniques employed for oily wastewater (oil-in-water; O/W emulsion) treatment, membrane-based separation is advantageous owing to its lower energy consumption, recycling, ease of operation, and wider scope of tuning the active layer chemistry for enhanced performance. In line with the possibilities of enhancing the performance of the membranes for efficient O/W emulsion separation, the current work is designed to yield five different variants of polyaniline (PANI) active layers with special surface wettability features (superhyrophilic and underwater superoleophobic) on a ceramic alumina support.

Insight into soft chemometric computational learning for modelling oily-wastewater separation efficiency and permeate flux of polypyrrole-decorated ceramic-polymeric membranes.

Reliable modeling of oily wastewater emphasizes the paramount importance of sustainable and health-conscious wastewater management practices, which directly aligns with the Sustainable Development Goals (SDG) while also meeting the guidelines of the World Health Organization (WHO). This research explores the efficiency of utilizing polypyrrole-coated ceramic-polymeric membranes to model oily wastewater separation efficiency (SE) and permeate flux (PF) based on established experimental procedures. In this area, computational simulation still needs to be explored.

Recent Advancements in Metal-Organic Framework-Based Membranes for Hydrogen Separation: A Review.

Metal-organic frameworks (MOFs) are promising porous materials that have huge potential for gas separation when put in the membrane configuration. MOFs have huge potential due to certain salient features of the MOFs such as excellent pore size, ease of tuning the pore chemistry, higher surface area, and chemical and thermal stabilities. MOFs have been explored for various gas separation and storage applications.

Recovery of Dissolved Hydrogen Sulfide from Various Wastewater Streams Using Membranes and Other Relevant Techniques: A Review.

Given the significance of dissolved HS, various techniques have been explored in the literature. The current review describes in detail the various membrane-based techniques, such as membrane contactors, for removing dissolved HS from various wastewater streams. Various types of hydrophobic membranes have been used, with more emphasis placed on PVDF hollow fiber membranes.

Fabrication of polyamide thin film composite membranes using aliphatic tetra-amines and terephthaloyl chloride crosslinker for organic solvent nanofiltration.

Given the huge significance of organic solvents in several industrial processes, the use of membranes for recovering the solvents has evolved into an industrially viable process. The current work has been focused on studying the effect of minor changes in the chemistry of the reacting monomers on the organic solvent nanofiltration/solvent resistance nanofiltration (OSN/SRNF) performance of the membranes. The two aliphatic amines with varying aliphatic chain lengths between primary and secondary amines were selected for this purpose.

Decoration of β-Cyclodextrin and Tuning Active Layer Chemistry Leading to Nanofiltration Membranes for Desalination and Wastewater Decontamination.

Given the huge potential of thin film composite (TFC) nanofiltration (NF) membranes for desalination and micro-pollutant removal, two different sets of six NF membranes were synthesized. The molecular structure of the polyamide active layer was tuned by using two different cross-linkers, terephthaloyl chloride (TPC) and trimesoyl chloride (TMC), reacted with tetra-amine solution containing β-Cyclodextrin (BCD). To further tune the structure of the active layers, the time duration of interfacial polymerization (IP) was varied from 1 to 3 min.

Removal of pharmaceutically active compounds from water sources using nanofiltration and reverse osmosis membranes: Comparison of removal efficiencies and in-depth analysis of rejection mechanisms.

Trace organic compounds from effluent streams are not completely removed by conventional purification techniques and hence, contaminating groundwater sources. Herein, we report the removal efficiency and rejection mechanisms of three common pharmaceutically active compounds (PhACs); caffeine (CFN), omeprazole (OMZ), and sulfamethoxazole (SMX), using commercial nanofiltration (NF) and reverse osmosis (RO) membranes with different surface characteristics. The RO membranes showed near-complete removal of all PhACs with rejection rates >99%.

Photocatalytic deactivation of sulphate reducing bacteria using visible light active CuO/TiO nanocomposite photocatalysts synthesized by ultrasonic processing.

Sulphate-reducing bacteria wreaks havoc to oil pipelines, as it is an active agent for scale formation in the oil production tubing, and plugging of reservoir rock around the oil wells, and this leads to the degradation of oil quality. In this work, we synthesized copper oxide/titanium dioxide nanocomposite photocatalysts with three different mass contents of copper oxide (10%, 20% and 30%) and used them as an effective photo-catalyst in the process of photo-catalytic deactivation of sulphate-reducing bacteria. The anchoring of copper oxide on titanium dioxide brought about the following positive attributes in copper oxide/titanium dioxide nanocomposite pertained to the photo-catalyst: (i) the material transformed to visible light active with the potential to harness the more efficient visible spectral region of the solar radiation, (ii) increased surface area on the photo-catalyst enhanced the number of active reaction sites in the material, and (iii) efficiently retarded the undesired photo-generated electron hole recombination to promote the photo-catalytic activity.

Fabrication of Photo-Responsive Mesh Membrane with Surface-Engineered Wettability for Oil-Water Separation and Photocatalytic Degradation of Organic Pollutants.

A photo-responsive TiO-coated stainless-steel mesh membrane (TiO@SSM), possessing unique surface wettability, was fabricated. This TiO@SSM membrane is found to be capable of separating oil and water from oily water and has the potential to carry out photocatalytic self-cleaning and/or the degradation of organic pollutants present in water. The fabrication of TiO@SSM is quite simple: titanium dioxide (TiO) nanoparticles were spray-coated onto stainless steel microporous mesh (SSM) substrates and annealed at the temperature of 500 °C.

An efficient and simple strategy for fabricating a polypyrrole decorated ceramic-polymeric porous membrane for purification of a variety of oily wastewater streams.

A ceramic-polymeric membrane was fabricated through in-situ oxidative polymerization of pyrrole (Py) on alumina (AlO) ceramic ultrafiltration support. The establishment of polypyrrole (PPy) active layer on the ceramic support led to a new PPy coated ceramic-polymeric membrane. Various salient features such as surface wettability, surface morphology, composition and functional goups of PPy coated ceramic-polymeric membrane were determined by various characterization techniques water contact angle (WCA), scanning electron microscopy (SEM), energy dispersive x-ray (EDX) analysis and attenuated total reflectance fourier transform infrared (ATR-FTIR).

Customization of surface wettability of nano-SiO by coating Trimethoxy(vinyl)silane modifier for oil-water separation: Fabrication of metal-based functional superwetting nanomaterial, characterizations and performance evaluation.

The wettability of nano-SiO surface was transformed from the inherent hydrophilicity to functional superhyderophobicity by coating Trimethoxy (vinyl)silane modifier, and the resultant surface showed contrasting wettability for water and oil (Superhydrophobic and Superoleophilic), which is a desired characteristic for the membranes used in oil-water separation. Initially Trimethoxy (vinyl)silane coated SiO nanoparticles (TMVS@SiO) were synthesized by hydrolysis and poly-condensation reactions, and this nano dispersion was spray coated on the annealed stainless-steel mesh surface, whose resulting hierarchical surface texture brought about the desired wettability, with the water-surface-air (θ) and oil-surface-air (θ) interfacial contact angles of 150° and 0° respectively. In addition to the wettability studies (contact angles), FTIR, morphological, and elemental characterizations of the TMVS@SiO coated surfaces were carried out to understand the alterations that have taken place on the TMVS@SiO surface that in turn rendered superhydrophobicity and superoleophilicity to the surface.

NH-CuO-MCM-41 covalently cross-linked multipurpose membrane for applications in water treatment: Removal of hazardous pollutants from water, water desalination and anti-biofouling performance.

The current study was planned to fabricate a new set of membranes to target multiple application areas such as desalting, removal of micropollutants and antibiofouling performance. In-situ incorporated copper oxide to MCM-41 (CuO-MCM-41) was synthesized and amine (-NH) functionalized by reacting with N1-(3-trimethoxy silylpropyl) diethylenetriamine (NTSDETA) yielding NH-CuO-MCM-41. Different concentrations of NH-CuO-MCM-41 were covalently cross-linked in polyamide active layer during interfacial polymerization (IP) between N, N'-bis(3-aminopropyl)ethylenediamine and terephthaloyl chloride (TPC) on polysulfone/poly ester terephthalate (PS/PET) support.

A Simple Approach to Fabricate Composite Ceramic Membranes Decorated with Functionalized Carbide-Derived Carbon for Oily Wastewater Treatment.

Membrane-based oil−water separation has shown huge potential as a remedy to challenge oily wastewater with ease and low energy consumption compared to conventional purification techniques. A set of new composite ceramic membranes was fabricated to separate surfactant-stabilized oil/water (O/W) emulsion. Carbide-derived carbon (CDC) was functionalized by 3-aminopropyltriethoxy silane (APTES) and subsequently deposited on a ceramic alumina support and impregnated with piperazine as an additional amine.

A review on super-wettable porous membranes and materials based on bio-polymeric chitosan for oil-water separation.

Appropriate surface wettability of membranes and materials are of an extreme importance for targeting separation of mixtures/emulsions such as oil from water or conversely water from oil. The development of super-wettable membranes and materials surfaces have shown remarkable potential for recovering water from oil-water emulsion while offering maximum resistance to fouling. The availability of clean and potable water has been regarded as an important global challenge for coming human generations.

Facile Modification of NF Membrane by Multi-Layer Deposition of Polyelectrolytes for Enhanced Fouling Resistance.

Fouling not only deteriorates the membrane structure but also compromises the quality of the permeate and has deleterious consequences on the membrane operation. In the current study, a commercial thin film composite nanofiltration membrane (NF90) was modified by sequentially depositing oppositely charged polycation (poly(allylamine hydrochloride)) and polyanion (poly(acrylic acid)) polyelectrolytes using the layer-by-layer assembly method. The water contact angle was decreased by ~10° after the coating process, indicating increased hydrophilicity.

Polyimide based super-wettable membranes/materials for high performance oil/water mixture and emulsion separation: A review.

This article reviews the application of highly heat and pressure resistant polyimide material for the development of membranes/materials that exhibit unique super-wettability, the characteristics pivotal for the efficient separation of oil-water mixture and emulsion. The polymerization of imide monomer in polyimide brings about the required porosity in the material, which in turn renders the crucial surface roughness, which is instrumental for establishing the desired super-wettability on the polyimide based membrane materials, in addition to the mechanical and thermal robustness. The membrane as the oil-water filtering medium can be either oil passing or water passing depends on the individual wettability of the membrane surface for oil and water, which in turn depend on the respective solid-liquid interfacial energy and the hierarchical surface roughness.

Structural and Magnetic Properties of CoNiGaGdFeO/ZnFeO Spinel Ferrite Nanocomposites: Comparative Study between Sol-Gel and Pulsed Laser Ablation in Liquid Approaches.

In this study, the samples of the ZnFeO (ZFO) spinel ferrites nanoparticles (SFNPs), CoNiGaGdFeO (CNGaGdFO) SFNPs and (CoNiGaGdFeO)/(ZnFeO) (: = 1:1, 1:2, 1:3, 2:1, 3:1 and 4:1) (CNGaGdFO)/(ZFO) spinel ferrite nanocomposites (NC) have been synthesized by both sol-gel and Green pulsed laser ablation in liquid (PLAL) approaches. All products were characterized by X-ray powder diffraction (XRD), scanning and transmission electron microscopies (SEM and TEM), elemental mappings and energy dispersive X-ray spectroscopy (EDX). It was objected to tune the magnetic properties of a soft spinel ferrite material with a softer one by mixing them with different fractions.

Semiconducting graphitic carbon nitride integrated membranes for sustainable production of clean water: A review.

Semiconducting membranes integrated with nanomaterials have placed themselves in new emerging researches tremendously for seawater desalination, oil-water separation, disinfection, removal of inorganic as well as organic pollutants. Howbeit, only nanoparticles unified membranes show quite a lot lags in their performance, although some of these particles associated with the demerits of high cost. In contrast, graphitic carbon nitride incorporated membranes offered improved aforementioned properties corresponding to absolute essential qualities such as cost-effective, environmentally friendly, easy-to-operate, green manufacturing, anti-fouling, and low energy consumption.

The SIMULATE ureteroscopy training curriculum: educational value and transfer of skills.

Objective: Different simulation modalities may be utilised in a curricular fashion to benefit from the strengths of each training model. The aim of this study is to evaluate a novel multi-modality ureterorenoscopy (URS) simulation curriculum in terms of educational value, content validity, transfer of skills and inter-rater reliability.

Methods: This international prospective study recruited urology residents (n = 46) with ≤ 10 URS experience and no prior simulation training.

Simulation-Based Training Models for Urolithiasis: A Systematic Review.

Urolithiasis is one of the most common presentations in urological practice and it is becoming increasingly important to provide structured, simulation-based training using validated training models. This systematic review aims to identify current simulation-based training models and to evaluate their validity and effectiveness. Following the PRISMA (Preferred Reporting Items for Systematic Reviews and Meta-Analyses) guidelines, a comprehensive search was performed on the Medline and EMBASE databases for English language articles published between 2000 and 2018 describing and/or assessing validity of simulation models for urolithiasis procedures.

Multifunctional membranes with super-wetting characteristics for oil-water separation and removal of hazardous environmental pollutants from water: A review.

Over the past few years, oil-water separation techniques have been widely researched due to influences of oil pollution. The oil pollution is significantly increasing day-by-day because of ever-increasing usage of oil in daily routine of humans and industrial activities. The separation of water from oil-water emulsions/mixtures through membrane technology has provided absolute necessary qualities such as low cost, eco-friendly, easy-operation and energy efficient.

Evaluation of bioactivities of zinc oxide, cadmium sulfide and cadmium sulfide loaded zinc oxide nanostructured materials prepared by nanosecond pulsed laser.

The present study reports the preparation of cadmium sulfide (CdS) loaded zinc oxide (ZnO) nanostructured semiconductor material and its anti-bioactivity studies against cancerous and fungus cells. For composite preparation, two different mass ratios of CdS (10 and 20%) were loaded on ZnO (10%CdS/ZnO, 20%CdS/ZnO) using a 532 nm pulsed laser ablation in water media. The structural and morphological analyses confirmed the successful loading of nanoscaled CdS on the surface of ZnO particles, ZnO particles were largely spherical with average size ~50 nm, while CdS about 12 nm in size.