Climate change and global warming necessitate the shift toward low-emission, carbon-free fuels. Although hydrogen boasts zero carbon content and high performance, its utilization is impeded by the complexities and costs involved in liquefaction, preservation, and transportation. Ammonia has emerged as a viable alternative that offers potential as a renewable energy storage medium and supports the global economy's decarbonization.
View Article and Find Full Text PDFChemical kinetics govern the dynamics of chemical systems leading towards chemical equilibrium. There are several general properties of the dynamics of chemical reactions such as the existence of disparate time scales and the fact that most time scales are dissipative. This causes a transient relaxation to lower dimensional attracting manifolds in composition space.
View Article and Find Full Text PDFPhys Chem Chem Phys
April 2018
A recently developed automatic reduction method for systems of chemical kinetics, the so-called Global Quasi-Linearization (GQL) method, has been implemented to study and reduce the dimensions of a homogeneous combustion system. The results of application of the GQL and the Quasi-Steady State Assumption (QSSA) are compared. A number of drawbacks of the QSSA are discussed, i.
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