Room-Temperature Persistent Phosphorescence of Aggregated Gold Nanoclusters under Molecular Crystal Confinements.

We report color-tunable and solvent-processable persistent fluorescence to phosphorescence switching at room temperature by doping gold nanoclusters (AuNCs) inside molecular crystals. This provides a significant insight into the tunability of the photoluminescence property of the dopant depending on the crystal environment and compactness of confinement, with the possibility of energy transfer from crystal to aggregated AuNCs. For test cases, we have doped histidine-stabilized AuNCs (HIS-AuNCs) inside histidine (HIS-AuNCs-HIS) and isophthalic acid (HIS-AuNCs-IPA) crystals, respectively, and glutathione-stabilized AuNCs (GSH-AuNCs) inside histidine crystals (GSH-AuNCs-HIS).

The Potential of Gadolinium Ascorbate Nanoparticles as a Safer Contrast Agent.

There have been health concerns raised against the use of gadolinium (Gd)-based magnetic resonance imaging contrast agents. The primary observation is that Gd ions are prone to leaking into the bloodstream, causing nephrogenic systemic fibrosis as one of the side effects. In addition, such leakage of the ions inhibits easy clearance from the body.