Unveiling Potential of Gallium Ferrite (GaFeO) as an Anode Material for Lithium-Ion Batteries.

Lithium-ion batteries (LIBs) serve as the backbone of modern technologies with ongoing efforts to enhance their performance and sustainability driving the exploration of new electrode materials. This study introduces a new type of alloy-conversion-based gallium ferrite (GFO: GaFeO) as a potential anode material for Li-ion battery applications. The GFO was synthesized by a one-step mechanochemistry-assisted solid-state method.

Self-assembly of magnetic colloids with radially shifted dipoles.

Anisotropic potentials in Janus colloids provide additional freedom to control particle aggregation into structures of different sizes and morphologies. In this work, we perform Brownian dynamics simulations of a dilute suspension of magnetic spherical Janus colloids with their magnetic dipole moments shifted radially towards the surface of the particle in order to gain valuable microstructural insight. Properties such as the mean cluster size, orientational ordering, and nucleation and growth are examined dynamically.

Steering Active Emulsions with Liquid Crystals.

Colloids dispersed in liquid crystals (LCs) diffuse preferentially along the LC director because this direction of displacement generates the lowest hydrodynamic drag. In this article, we report on the active transport of micrometer-sized nematic droplets of 4'-pentyl-4-biphenylcarbonitrile (5CB) propelled through a continuous LC phase formed from aqueous solutions of disodium cromoglycate (DSCG) by Marangoni stresses (generated through the addition of sodium dodecyl sulfate (SDS)). We observe the nematic droplets to exhibit motion guided by the continuous LC phase, but in contrast to passive diffusion, the LC droplets move preferentially in a direction perpendicular to the continuous-phase LC director.

Measuring, Modeling, and Predicting the Magnetic Assembly Rate of 2D-Staggered Janus Particle Chains.

The assembly of magnetic Janus particles in a quasi-two-dimensional environment with a dipole moment shifted from the center and oriented perpendicular to the Janus cap height is studied with optical microscopy and found to adhere to a general model accounting for the particle dipole strength, the particle Brownian dynamics, the initial concentration, and, most importantly, the magnetic dipole shift. The particle aggregates are treated as diffusing spherocylinders with length and width dependent on the magnetic dipole shift. Aggregation occurs irreversibly once particle aggregates enter within a distance at which Brownian and dipole forces are equal, defined as the capture distance.

Self-assembly of magnetic colloids with shifted dipoles.

The self-assembly of colloidal magnetic Janus particles with a laterally displaced (or shifted), permanent dipole in a quasi-two-dimensional system is studied using Brownian dynamics simulations. The rate of formation of clusters and their structures are quantified for several values of dipolar shift from the particle center, which is nondimensionalized using the particle's radius so that it takes values ranging from 0 to 1, and examined under different magnetic interaction strengths relative to Brownian motion. For dipolar shifts close to 0, chain-like structures are formed, which grow at long times following a power law, while particles of shift higher than 0.

Dynamics of a magnetic active Brownian particle under a uniform magnetic field.

The dynamics of a magnetic active Brownian particle undergoing three-dimensional Brownian motion, both translation and rotation, under the influence of a uniform magnetic field is investigated. The particle self-propels at a constant speed along its magnetic dipole moment, which reorients due to the interplay between Brownian and magnetic torques, quantified by the Langevin parameter α. In this work, the time-dependent active diffusivity and the crossover time (τ^{cross})-from ballistic to diffusive regimes-are calculated through the time-dependent correlation function of the fluctuations of the propulsion direction.

Shear-Induced Alignment of Janus Particle Lamellar Structures.

Control over the alignment of colloidal structures plays a crucial role in advanced reconfigurable materials. In this work, we study the alignment of Janus particle lamellar structures under shear flow via Brownian dynamics simulations. Lamellar alignment (orientation relative to flow direction) is measured as a function of the Péclet number (Pe)-the ratio of the viscous shear to the Brownian forces-the particle volume fraction, and the strength of the anisotropic interaction potential made dimensionless with thermal energy.

Active Janus Particles at Interfaces of Liquid Crystals.

We report an investigation of the active motion of silica-palladium Janus particles (JPs) adsorbed at interfaces formed between nematic liquid crystals (LCs) and aqueous phases containing hydrogen peroxide (HO). In comparison to isotropic oil-aqueous interfaces, we observe the elasticity and anisotropic viscosity of the nematic phase to change qualitatively the active motion of the JPs at the LC interfaces. Although contact line pinning on the surface of the JPs is observed to restrict out-of-plane rotational diffusion of the JPs at LC interfaces, orientational anchoring of nematic LCs on the silica (planar) and palladium (homeotropic) hemispheres biases JP in-plane orientations to generate active motion almost exclusively along the director of the LC at low concentrations of HO (0.

Enhanced Diffusion of Passive Tracers in Active Enzyme Solutions.

Colloidal suspensions containing microscopic swimmers have been the focus of recent studies aimed at understanding the principles of energy transfer in fluidic media at low Reynolds number conditions. Going down in scale, active enzymes have been shown to be force-generating, nonequilibrium systems, thus offering opportunity to examine energy transfer at the ultralow Reynolds number regime. By monitoring the change of diffusion of inert tracers dispersed in active enzyme solutions, we demonstrate that the nature of energy transfer in these systems is similar to that reported for larger microscopic active systems, despite the large differences in scale, modes of energy transduction, and propulsion.

Rich Janus colloid phase behavior under steady shear.

We study the assembly of single-patch colloidal Janus particles under steady shear flow via Brownian dynamics simulations. In the absence of flow, by varying the Janus patch size and the range and strength of the anisotropic interaction potential, Janus colloids form different aggregates such as micelles, wormlike clusters, vesicles and lamellae. Under shear flow we observe rearrangement, deformation, and break-up of aggregates.

Micromotors Powered by Enzyme Catalysis.

Active biocompatible systems are of great current interest for their possible applications in drug or antidote delivery at specific locations. Herein, we report the synthesis and study of self-propelled microparticles powered by enzymatic reactions and their directed movement in substrate concentration gradient. Polystyrene microparticles were functionalized with the enzymes urease and catalase using a biotin-streptavidin linkage procedure.

Osmotic propulsion: the osmotic motor.

A model for self-propulsion of a colloidal particle--the osmotic motor--immersed in a dispersion of "bath" particles is presented. The nonequilibrium concentration of bath particles induced by a surface chemical reaction creates an osmotic pressure imbalance on the motor causing it to move. The ratio of the speed of reaction to that of diffusion governs the bath particle distribution which is employed to calculate the driving force on the motor, and from which the self-induced osmotic velocity is determined.