Publications by authors named "U Zammit"

In the manufacture of ancient books, it was quite common to insert written scraps belonging to earlier library material into bookbindings. For scholars like codicologists and paleographers, it is extremely important to have the possibility of reading the text lying on such scraps without dismantling the book. In this regard, in this paper, we report on the detection of these texts by means of infrared (IR) pulsed thermography (PT), which, in recent years, has been specifically proven to be an effective tool for the investigation of Cultural Heritage.

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In the present work, by means of the photopyroelectric calorimetric investigations in liquid crystal/naphtopyran (NP) molecule mixtures, the effect of the photoisomerization of NP by UV light on the critical behavior of specific heat could be studied over the smectic-nematic phase transition. It is shown that the UV light irradiation of the sample can shift the critical exponent from a non-universal value typical of the non-irradiated mixture to one close to that of the 3D-XY universality class, predicted for such a transition. This witnesses the optically triggered reduction of the coupling between the smectic and nematic order parameters responsible for the deviation from the XY-like behavior.

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In this work we use a photopyroelectric calorimetric set up to analyze the transformations occurring in thin samples of liquid crystal-microemulsion system by combining the results of the simultaneously performed high temperature resolution polarization microscopy observations and the temperature dependence of the specific heat, and of the thermal conductivity. This enabled an accurate direct correlation of the observations concerning the different measured quantities for a most comprehensive interpretation of the obtained results. It is found that the I-N conversion progresses in the entire nematic range because of the micelles expelled from the nucleating nematic volumes remaining confined in the residual isotropic material.

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We have studied the specific heat and the thermal conductivity in a 4-(n-octyl)-4'-cyanobiphenyl liquid crystal (LC)-photochromic molecules mixture, before, during, and after the photo-activation of the dispersed photochromic molecules, over both the smectic A-nematic and the nematic-isotropic phase transitions. The evaluation of the specific heat has enabled the determination of the changes of the phase transition characteristics induced by the photochromic molecules photoisomerization, while that of the thermal conductivity could be used to monitor the modifications induced in the average LC molecular orientation. The polarization microscopy imaging of the sample texture constituted a valuable support for the interpretation of the obtained thermal conductivity results.

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The behaviour of the thermal effusivity squared over the glass transition in polystyrene is measured over a considerable frequency range using a novel dual beam front detection photopyroelectric configuration, which ensures a very effective processing of the obtained signal. This has enabled the detection of the very small changes taking place in such a parameter, despite the non-favourable sensitivity conditions due to the large mismatch between the thermal effusivities of the pyroelectric transducer and of the sample. The effect of the thermal contact resistance between the sample and the pyroelectric detector is also considered and discussed.

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