Publications by authors named "U Kuhn"

Daytime HONO photolysis is an important source of atmospheric hydroxyl radicals (OH). Knowledge of HONO formation chemistry under typical haze conditions, however, is still limited. In the Multiphase chemistry experiment in Fogs and Aerosols in the North China Plain in 2018, we investigated the wintertime HONO formation and its atmospheric implications at a rural site Gucheng.

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As a major socio-historical event affecting different aspects of life, the COVID-19 pandemic presents a unique opportunity to study how different population groups adapt. We investigate the impact of this crisis on the evolution of perceived stress in the short and medium term in Switzerland, using data of the Swiss Household Panel from 2016 to early 2021, which include annual measures of perceived stress and a study between waves, conducted in May and June 2020 at the end of the first semi-lockdown. Using the longitudinal structure of the data with pre-crisis measurements, we estimate pooled OLS, fixed effects and first difference models, which include socio-demographic variables, life events, socio-economic status, work-related variables, stress-reducing resources and restrictions in place.

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In this study, a newly developed high-strength cast Fe81Cr15V3C1 (wt%) steel with a high resistance against dry abrasion and chloride-induced pitting corrosion is presented. The alloy was synthesized through a special casting process that yielded high solidification rates. The resulting fine, multiphase microstructure is composed of martensite, retained austenite and a network of complex carbides.

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A high-performance tool steel with the nominal composition Fe85Cr4Mo8V2C1 (wt%) was processed by three different manufacturing techniques with rising cooling rates: conventional gravity casting, centrifugal casting and an additive manufacturing process, using laser powder bed fusion (LPBF). The resulting material of all processing routes reveals a microstructure, which is composed of martensite, austenite and carbides. However, comparing the size, the morphology and the weight fraction of the present phases, a significant difference of the gravity cast samples is evident, whereas the centrifugal cast material and the LPBF samples show certain commonalities leading finally to similar mechanical properties.

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Accurate determination of acidity (pH) and ion activities in aqueous droplets is a major experimental and theoretical challenge for understanding and simulating atmospheric multiphase chemistry. Here, we develop a ratiometric Raman spectroscopy method to measure the equilibrium concentration of sulfate (SO) and bisulfate (HSO) in single microdroplets levitated by aerosol optical tweezers. This approach enables determination of ion activities and pH in aqueous sodium bisulfate droplets under highly supersaturated conditions.

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