Metal-Organic Framework-Derived Electrocatalysts Competent for the Conversion of Acrylonitrile to Adiponitrile.

Electrochemical conversion of acrylonitrile (AN) to produce adiponitrile (ADN), the raw material for the production of Nylon 66, has become a crucial process owing to the increasing market demand of Nylon 66. Although the metallic Pb or Cd electrodes are commonly used for this reaction, the use of electrocatalysts or electrodes modified with catalysts has been barely investigated. In this study, nanoporous and electrically conductive metal-organic framework (MOF)-derived materials composed of Pb, PbO, and carbon are synthesized by carbonizing a Pb-based MOF through thermal treatments, and these MOF-derived materials are served as electrocatalysts for the electrosynthesis of ADN.

Probing the electronic and ionic transport in topologically distinct redox-active metal-organic frameworks in aqueous electrolytes.

Three topologically distinct zirconium-based metal-organic frameworks (Zr-MOFs) constructed from redox-innocent linkers, MOF-808, defective UiO-66, and CAU-24, are synthesized, and the spatially dispersed redox-active manganese sites are post-synthetically immobilized on the hexa-zirconium nodes of these Zr-MOFs. The crystallinity, morphology, porosity, manganese loading, and bulk electrical conductivity of each material are studied. The redox-hopping-based electrochemical reaction between the installed Mn(III) and Mn(IV) occurring within the thin films of these MOFs in aqueous electrolytes is investigated, in the presence of various concentrations of NaSO in the electrolytes.

Proton-Conductive Cerium-Based Metal-Organic Frameworks.

In this study, proton-conducting behaviors of a cerium-based metal-organic framework (MOF), Ce-MOF-808, its zirconium-based isostructural MOF, and bimetallic MOFs with various Zr-to-Ce ratios are investigated. The significantly increased proton conductivity (σ) and decreased activation energy () are obtained by substituting Zr with Ce in the nodes of MOF-808. Ce-MOF-808 achieves a σ of 4.