Colloidal High Entropy Alloy Nanoparticles: Synthetic Strategies and Electrocatalytic Properties.

High entropy alloy (HEA) nanoparticles (NPs) have attracted much attention recently due to their unprecedented chemical properties. As such, HEA NPs have been used as materials with superior activity toward electrocatalytic applications. Specifically, solid solutions that form randomly mixed single-phased structures have received the most focus in the early stages of HEA NP development for their entropic-driven design and multifunctionality.

New Insights into the ORR Catalysis on Pt Alloy Nanoparticles from an Element Specific -Band Analysis.

Bolstered by their unique atomic structures and tailored compositions, nanoalloys exhibit extraordinary properties making them ideal materials to solve challenges in energy storage and conversion catalysis. However, a quantitative description of the structure-property relationships using an accurate descriptor-based model for nanoalloys, ranging from bimetallic to multimetallic compositions, is needed to drive efficient material design toward high-performance catalysis. In this work, we highlight the electronic property and catalytic activity relationship from an element specific -band analysis of Pt-based alloy catalysts using X-ray absorption near-edge spectroscopy (XANES).

Unveiling the Nanocluster Conversion Pathway for Highly Monodisperse InAs Colloidal Quantum Dots.

Colloidal quantum dots (CQDs) have garnered significant attention in nanoscience and technology, with a particular emphasis on achieving high monodispersity in their synthesis. Recent advances in understanding the chemistry of reaction intermediates such as magic-sized nanoclusters (MSC) have paved the way for innovative synthetic strategies. Notably, monodisperse CQDs of various compositions, including indium phosphide, indium arsenide, and cadmium chalcogenide, have been successfully prepared using nanocluster intermediates as single-source precursors.

Detection and impact of short-range order in medium/high-entropy alloys.

Medium/High-entropy alloys (MEAs/HEAs) have attracted much attention during the past two decades and have been studied extensively owing to their excellent physical and mechanical properties. These materials form simple lattice structures and thermodynamically favored single-phase solutions. Despite having a single-phase, the local structure of MEAs/HEAs still contain some degree of order.