Fit-for-purpose treatment goals for produced waters in shale oil and gas fields.

Hydraulic fracturing (HF), or "fracking," is the driving force behind the "shale gas revolution," completely transforming the United States energy industry over the last two decades. HF requires that 4-6 million gallons per well (15,000-23,000 m/well) of water be pumped underground to stimulate the release of entrapped hydrocarbons from unconventional (i.e.

Lab-simulated downhole leaching of formaldehyde from proppants by high performance liquid chromatography (HPLC), headspace gas chromatography-vacuum ultraviolet (HS-GC-VUV) spectroscopy, and headspace gas chromatography-mass spectrometry (HS-GC-MS).

The ability of different methods to analyze formaldehyde and other leachates from proppants was investigated under lab-simulated downhole conditions. These methods include high performance liquid chromatography (HPLC), headspace gas chromatography-vacuum ultraviolet spectroscopy (HS-GC-VUV), and headspace gas chromatography-mass spectrometry (HS-GC-MS). Two different types of resin-coated proppants, phenol-formaldehyde- and polyurethane-based, were examined.