Organic Long-Persistent Luminescence from a Single-Component Aggregate.

Long-persistent luminescence (LPL), also known as afterglow, is a phenomenon in which the material shows long-lasting luminescence after the cessation of the excitation source. The research of LPL continues to attract much interest due to its fundamental nature and its potential in the development of the next generation of functional materials. However, most of the current LPL materials are multicomponent inorganic systems obtained after harsh synthetic procedures and often use rare-earth metals.

Two Are Better Than One: A Design Principle for Ultralong-Persistent Luminescence of Pure Organics.

Because of their innate ability to store and then release energy, long-persistent luminescence (LPL) materials have garnered strong research interest in a wide range of multidisciplinary fields, such as biomedical sciences, theranostics, and photonic devices. Although many inorganic LPL systems with afterglow durations of up to hours and days have been reported, organic systems have had difficulties reaching similar timescales. In this work, a design principle based on the successes of inorganic systems to produce an organic LPL (OLPL) system through the use of a strong organic electron trap is proposed.

Boosting the efficiency of organic persistent room-temperature phosphorescence by intramolecular triplet-triplet energy transfer.

Persistent luminescence is a fascinating phenomenon with exceptional applications. However, the development of organic materials capable of persistent luminescence, such as organic persistent room-temperature phosphorescence, lags behind for their normally low efficiency. Moreover, enhancing the phosphorescence efficiency of organic luminophores often results in short lifetime, which sets an irreconcilable obstacle.

Rational design of red AIEgens with a new core structure from non-emissive heteroaromatics.

The development of new aggregation-induced emission (AIE) systems is a hot research topic, from which functional materials with diversified structures and properties are derived. Here, based on rare, non-emissive and highly electron-withdrawing heteroaromatics of 1,4,5,8-tetraazaanthracene (TAA), experimental and theoretical studies reveal that attaching phenyl rotors to TAA is crucial to creating a new N-type AIE core structure. Furthermore, by covalent attachment of electron-donating aromatic amines to the peripheries of the AIE core, red AIEgens could be obtained readily, which exhibit excellent photostability for long-term lysosome tracking.