Investigation on luminescence photoswitching stability in diarylethene-perovskite quantum dot hybrids.

Perovskite quantum dots (pQDs) have gathered a lot of attention because of their outstanding optoelectronic properties. Photoswitchable pQDs have the potential for application in single particle optical memories and bio-imaging. Hybrids of photochromic diarylethenes (DAE) and pQDs show a luminescence photoswitching property, however, the cycle stability in such systems is low because of photoinduced electron transfer (PET) from pQDs to DAE.

Internal Heavy-Atom Effect on Visible-Light-Induced Cyclization Reaction in Diarylethene-Perylenebisimide Dyads.

All-visible-light switchable diarylethene-perylenebisimide (DAE-PBI) dyads having bromine heavy atoms in the molecule were designed and synthesized. Very recently, we found a unique visible-light-induced cyclization reaction in a DAE-PBI dyad. The dyad exhibited reversible cyclization and cycloreversion reactions upon alternate irradiation with green (500-550 nm) and red (>600 nm) light.