SiO is one of the most fundamental constituents in planetary bodies, being an essential building block of major mineral phases in the crust and mantle of terrestrial planets (1-10 M). Silica at depths greater than 300 km may be present in the form of the rutile-type, high pressure polymorph stishovite (P4/mnm) and its thermodynamic stability is of great interest for understanding the seismic and dynamic structure of planetary interiors. Previous studies on stishovite via static and dynamic (shock) compression techniques are contradictory and the observed differences in the lattice-level response is still not clearly understood.
View Article and Find Full Text PDFActa Crystallogr B Struct Sci Cryst Eng Mater
April 2019
Petzite, AgAuTe, crystallizes in the space group I432, which is a Sohncke type of space group where chiral crystal structures can occur. The structure refinement of petzite reported long ago [Frueh (1959). Am.
View Article and Find Full Text PDFPre-edge peaks in 3d transition-metal element (Sc, Ti, V, Cr and Mn) K-edge XANES (X-ray absorption near-edge structure) spectra in AO (A = Ti and V), AO (A = Sc, Cr and Mn) and AO (A = Mn) are measured at various temperatures. Quantitative comparisons for the XANES spectra were investigated by using absorption intensity invariant point normalization. The energy position of the difference peak (D peak) is obtained from the difference between the low- and high-temperature XANES spectra.
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