Correction: Fe Mössbauer spectroscopy and high-pressure structural analysis for the mechanism of pressure-induced unique magnetic behaviour in (cation)[FeFe(dto)] (cation = PhP and PrPhP; dto = 1,2-dithiooxalato).

Correction for 'Fe Mössbauer spectroscopy and high-pressure structural analysis for the mechanism of pressure-induced unique magnetic behaviour in (cation)[FeFe(dto)] (cation = PhP and PrPhP; dto = 1,2-dithiooxalato)' by Ryosuke Taniai , , 2023, , 8368-8375.

Probing thermal dissipation dimensionality to laser ablation in the pulse duration range from 300 fs to 1 µs.

We propose a quantitative method to determine the thermal dissipation dimensionality to laser ablation. We derived an analytical expression for the melting condition due to a single pulse for arbitrary spot diameters and pulse durations, which explicitly contains the dimensionality of the thermal diffusion process. As a demonstration, we compared the analytical expression with multi-shot ablation thresholds measured over pulse durations of more than six orders of magnitude for copper.

Fe Mössbauer spectroscopy and high-pressure structural analysis for the mechanism of pressure-induced unique magnetic behaviour in (cation)[FeFe(dto)] (cation = PhP and PrPhP; dto = 1,2-dithiooxalato).

A mixed-valence iron(II,III) coordination polymer, (PhP)[FeFe(dto)] (2; PhP = tetraphenylphosphonium, dto = 1,2-dithiooxalato), exhibits a thermal hysteresis loop and a low temperature shift of the ferromagnetic phase transition temperature, with increasing pressure. The latter magnetic behaviour can also be observed in a novel compound (PrPhP)[FeFe(dto)] (3; PrPhP = -propyltriphenylphosphonium). To understand the structural information under pressure, we performed high-pressure powder X-ray diffraction, and the result suggests that there was no structural phase transition for either compound.

Time-resolved EPR characterization of a folded conformation of photoinduced charge-separated state in porphyrin-fullerene dyad bridged by diphenyldisilane.

For development of the molecular solar-energy conversion systems, it is crucial to investigate how both the molecular geometry and electronic structure of electron donor-bridge-acceptor (D-B-A) molecules contribute to the electronic coupling for the charge-separation (CS) and charge-recombination (CR) processes. In a D-B-A system of a porphyrin-fullerene dyad (ZnP-C(60)) bridged by a diphenyldisilane spacer, we have characterized one specific folded molecular conformation in the CS state among several existing conformations using the time-resolved electron paramagnetic resonance (TREPR) method at low temperature. To determine the molecular conformation and spin-spin exchange coupling of the CS state, we have considered (1) the electron spin polarization transfer from the excited triplet state of the C(60) moiety to the CS state and (2) the sublevel-selective spin relaxations and CR in the CS state.