In this work, a fresh approach has been proposed for the efficient transfer of gold nanoparticles (AuNPs) from an aqueous to organic phase by the metathesis reaction or anion exchange reaction. Here, we synthesized ionic liquid 1-butyl 3-hexadecyl imidazolium bromide [CCIm]Br-stabilized AuNPs which exhibit excellent stability in solution. Transfer of Au@[CCIm]Br from an aqueous to organic phase was investigated by the metathesis reaction with different hydrophobic ionic liquid-forming salts such as LiNTf, LiClO, and KPF.
View Article and Find Full Text PDFLithium ion batteries (LIBs) with polymer based electrolytes have attracted enormous attention due to the possibility of fabricating intrinsically safer and flexible devices. However, economical and eco-friendly sustainable technology is an oncoming challenge to fulfill the ever increasing demand. To circumvent this issue, we have developed a gel polymer electrolyte (GPE) based on renewable polymers like cellulose triacetate and poly(polyethylene glycol methacrylate) p(PEGMA) using a photo polymerization technique.
View Article and Find Full Text PDFLithium ion batteries (LIB) are the most promising energy storage systems for portable electronics and future electric or hybrid-electric vehicles. However making them safer, cost effective and environment friendly is the key challenge. In this regard, replacing petro-derived materials by introducing renewable biomass derived cellulose derivatives and lignin based materials into the battery system is a promising approach for the development of green materials for LIB.
View Article and Find Full Text PDF