Standardized Electric-Field-Resolved Molecular Fingerprinting.

Field-resolved infrared spectroscopy (FRS) of impulsively excited molecular vibrations can surpass the sensitivity of conventional time-integrating spectroscopies, owing to a temporal separation of the molecular signal from the noisy excitation. However, the resonant response carrying the molecular signal of interest depends on both the amplitude and phase of the excitation, which can vary over time and across different instruments. To date, this has compromised the accuracy with which FRS measurements could be compared, which is a crucial factor for practical applications.

Designing broadband dispersive mirrors in the mid-infrared spectral range: a theoretical study.

The study reports practically important and interesting results on designing dispersive mirrors (DMs) operating in the mid-infrared spectral range from 3 to 18 µm. The admissible domains of the most important design specifications, the mirror bandwidth and group delay variation, were constructed. Estimations of the required total coating thickness, thickness of the thickest layer, and expected number of layers are obtained.

Optical Interference Coating Design Contest 2022: a black box coating and a filter for an outdoor 3D cinema challenge [invited].

The design problems for the Optical Interference Coating (OIC) 2022 Topical Meeting include black box coatings to reverse engineer and a pair of white-balanced, multi-bandpass filters for three-dimensional cinema projection in cold and hot outdoor environments. There were 14 designers from China, France, Germany, Japan, Russia, and the United States, submitting 32 total designs for problems A and B. The design problems and the submitted solutions are described and evaluated.

Reverse engineering of e-beam deposited optical filters based on multi-sample photometric and ellipsometric data.

A post-production characterization approach based on spectral photometric and ellipsometric data related to a specially prepared set of samples is proposed. Single-layer (SL) and multilayer (ML) sets of samples presenting building blocks of the final sample were measured ex-situ, and reliable thicknesses and refractive indices of the final ML were determined. Different characterization strategies based on ex-situ measurements of the final ML sample were tried, reliability of their results was compared, and the best characterization approach for practical use, when preparation of the mentioned set of samples would be a luxury, is proposed.

Ultra-rapid electro-optic sampling of octave-spanning mid-infrared waveforms.

We demonstrate ultra-rapid electro-optic sampling (EOS) of octave-spanning mid-infrared pulses centered at 9 μm, implemented by mechanically scanning a mirror with a sonotrode resonating at 19 kHz (forward and backward acquisition at 38 kHz). The instrument records the infrared waveform with a spectral intensity dynamic range of 1.6 × 10 for a single scan over a 1.

Molecular Origin of Blood-Based Infrared Spectroscopic Fingerprints*.

Infrared spectroscopy of liquid biopsies is a time- and cost-effective approach that may advance biomedical diagnostics. However, the molecular nature of disease-related changes of infrared molecular fingerprints (IMFs) remains poorly understood, impeding the method's applicability. Here we probe 148 human blood sera and reveal the origin of the variations in their IMFs.

Stability of person-specific blood-based infrared molecular fingerprints opens up prospects for health monitoring.

Health state transitions are reflected in characteristic changes in the molecular composition of biofluids. Detecting these changes in parallel, across a broad spectrum of molecular species, could contribute to the detection of abnormal physiologies. Fingerprinting of biofluids by infrared vibrational spectroscopy offers that capacity.

Design, fabrication and measurement of highly-dispersive mirrors with total internal reflection.

High group delay dispersion (GDD) is often required for ultrafast laser applications. To achieve GDD level higher than -10000 fs in a single mirror setting is difficult due to the high sensitivity to unavoidable production inaccuracies. To overcome the problem, total internal reflection (TIR) based dispersive mirrors have been proposed in theory.

Optimum Sample Thickness for Trace Analyte Detection with Field-Resolved Infrared Spectroscopy.

The strong absorption of liquid water in the infrared (IR) molecular fingerprint region constitutes a challenge for applications of vibrational spectroscopy in chemistry, biology, and medicine. While high-power IR laser sources enable the penetration of ever thicker aqueous samples, thereby mitigating the detrimental effects of strong attenuation on detection sensitivity, a basic advantage of heterodyne-measurement-based methods has-to the best of our knowledge-not been harnessed in broadband IR measurements to date. Here, employing field-resolved spectroscopy (FRS), we demonstrate in theory and experiment fundamental advantages of techniques whose signal-to-noise ratio (SNR) scales linearly with the electric field over those whose SNR scales linearly with radiation intensity, including conventional Fourier-transform infrared (FTIR) and direct absorption spectroscopy.

Optical interference coating design contest 2019: a non-polarizing beam splitter and a color-mixing challenge [Invited].

A non-polarizing beam splitter and a light color-mixing challenge were the topics of the design contest held in conjunction with the 2019 Optical Interference Coatings topical meeting of the Optical Society of America. A total of 10 designers from China, France, Germany, Japan, and the United States submitted over 70 designs for problems A and B. The design problems and the submitted solutions are described and evaluated.

Broadband phase-shifting mirrors for ultrafast lasers.

Metal-dielectric phase-shifting multilayer optical elements have been developed, providing broadband, virtually dispersion-free polarization manipulation down to the few-cycle level. These optical elements are / mirrors that operate in the spectral range from 500 to 100 nm, exhibiting reflectance higher than 95%, and a differential phase shift between the s- and p-polarization of about 90° distributed over four bounces. The mirrors have been designed, produced, and reliably characterized based on spectral photometric and ellipsometric data using a non-parametric approach as well as a multi-oscillator model.

Deep search methods for multilayer coating design.

Many existing well-known multilayer design methods are based on so-called greedy algorithms. New deep search algorithms developed for needle optimization, gradual evolution, and design cleaner methods are presented. The algorithms possess machine learning features.

Characterization of e-beam evaporated Ge, YbF, ZnS, and LaF thin films for laser-oriented coatings.

Thin films of Ge, ZnS, , and produced using e-beam evaporation on ZnSe and Ge substrates were characterized in the range of 0.4-12 µm. It was found that the Sellmeier model provides the best fit for refractive indices of ZnSe substrate, ZnS, and films; the Cauchy model provides the best fit for film.

Field-resolved infrared spectroscopy of biological systems.

The proper functioning of living systems and physiological phenotypes depends on molecular composition. Yet simultaneous quantitative detection of a wide variety of molecules remains a challenge. Here we show how broadband optical coherence opens up opportunities for fingerprinting complex molecular ensembles in their natural environment.

Complementary Si/SiO dispersive mirrors for 2-4 µm spectral range.

Complementary pair of dispersive multilayers operating in the 2-4 µm spectral range were designed and produced for the first time. The mirrors comprise layers of Si and SiO thin-film materials. The pair exhibits unparalleled reflectance exceeding 99.

Broadband dispersive Ge/YbF mirrors for mid-infrared spectral range.

Broadband dispersive mirrors operating in the mid-infrared spectral range of 6.5-11.5 μm are developed for the first time, to the best of our knowledge.

Cavity-enhanced noncollinear high-harmonic generation.

Femtosecond enhancement cavities have enabled multi-10-MHz-repetition-rate coherent extreme ultraviolet (XUV) sources with photon energies exceeding 100 eV - albeit with rather severe limitations of the net conversion efficiency and of the duration of the XUV emission. Here, we explore the possibility of circumventing both these limitations by harnessing spatiotemporal couplings in the driving field, similar to the "attosecond lighthouse," in theory and experiment. Our results predict dramatically improved output coupling efficiencies and efficient generation of isolated XUV attosecond pulses.

Comparative study of NIR-MIR beamsplitters based on ZnS/YbF and Ge/YbF.

Two beamsplitters operating across the near-infrared (770-1050 nm) and mid-infrared (4-8 µm) spectral ranges are developed. For the first time, the beamsplitters based on thin-film materials combinations of ZnS/YbF and Ge/YbF are investigated. The multilayers operate at the Brewster angle of ZnSe substrate.

2/3 octave Si/SiO infrared dispersive mirrors open new horizons in ultrafast multilayer optics.

Dispersive mirrors operating in a broadband infrared spectral range are reported for the first time. The mirrors are based on Si/SiO thin-film materials. The coatings exhibit reflectance exceeding 99.

10 W CEP-stable few-cycle source at 2 µm with 100 kHz repetition rate.

We developed a high repetition rate optical parametric chirped-pulse amplification (OPCPA) laser system based on fiber-laser-seeded Innoslab to generate few-cycle pulses around 2 µm with passively stable carrier-envelope phase (CEP) by difference frequency generation (DFG). Incorporating a piezo mirror before the DFG stage permits rapid CEP control. The OPCPA system is seeded by a stable supercontinuum generated in bulk material with the picosecond Innoslab pulses.

Nonlinear pulse compression in a gas-filled multipass cell.

We present an efficient method for compressing sub-picosecond pulses at 200 W average power with 2 mJ pulse energy in a multipass cell filled with different gases. We demonstrate spectral broadening by more than a factor of five using neon, argon, and nitrogen as nonlinear media. The 210 fs input pulses are compressed down to 37 fs and 35 GW peak power with a beam quality factor of 1.

Multi-watt, multi-octave, mid-infrared femtosecond source.

Spectroscopy in the wavelength range from 2 to 11 μm (900 to 5000 cm) implies a multitude of applications in fundamental physics, chemistry, as well as environmental and life sciences. The related vibrational transitions, which all infrared-active small molecules, the most common functional groups, as well as biomolecules like proteins, lipids, nucleic acids, and carbohydrates exhibit, reveal information about molecular structure and composition. However, light sources and detectors in the mid-infrared have been inferior to those in the visible or near-infrared, in terms of power, bandwidth, and sensitivity, severely limiting the performance of infrared experimental techniques.

Compact and flexible harmonic generator and three-color synthesizer for femtosecond coherent control and time-resolved studies.

Intense, multi-color laser fields permit the control of the ionization of atoms and the steering of electron dynamics. Here, we present the efficient collinear creation of the second and third harmonic of a 790 nm femtosecond laser followed by a versatile field synthesizer for the three color fields' composition. Using the device, we investigate the strong-field ionization of neon by fields composed of the fundamental, and the second or third harmonic.

Experimental and numerical study of the nonlinear response of optical multilayers.

Dielectric multilayer coatings exhibiting steep reflectance in an extremely narrow transition zone, highly sensitive to any variations of layer refractive indices and therefore suitable for studying the nonlinear properties are produced and characterized. Increase of reflectance at growing intensity reveals the presence of the optical Kerr effect. A new method calculating intensity dependent spectral characteristics of multilayer optical coatings in the case of nonlinear interaction with high intensity laser pulses is developed.

Synthesis, fabrication and characterization of a highly-dispersive mirrors for the 2 µm spectral range.

We report a challenging design, fabrication and post-production characterization problem of a dispersive mirror supporting the spectral range from 2000 nm to 2200 nm and providing a group delay dispersion of -1000 fs. The absolute reflectance in the working range is over 99.95%.