In the process of acidizing carbonate reservoirs, dissolution is employed for reservoir modification to enhance recovery rates. This study establishes a numerical model at the pore scale for acid-rock reaction flow based on a microscopic continuum medium model, integrating phase-field theory and component transport models. Subsequently, the results of the Darcy-Brinkman-Stokes model are compared to those of the arbitrary Lagrange-Euler method to validate the accuracy of the model.
View Article and Find Full Text PDFMg-S batteries hold great promise as a potential alternative to Li-based technologies. Their further development hinges on solving a few key challenges, including the lower capacity and poorer cycling performance when compared to Li counterparts. At the heart of the issues is the lack of knowledge on polysulfide chemical behaviors in the Mg-S battery environment.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
August 2023
ACS Appl Mater Interfaces
May 2023
Next-generation materials for fast ion conduction have the potential to revolutionize battery technology. Metal-organic frameworks (MOFs) are promising candidates for achieving this goal. Given their structural diversity, the design of efficient MOF-based conductors can be accelerated by a detailed understanding and accurate prediction of ion conductivity.
View Article and Find Full Text PDFDuctal carcinoma in situ (DCIS) of the breast is a non-invasive tumour that has the potential to progress to invasive ductal carcinoma (IDC). Thus, it represents a treatment dilemma: alone it does not present a risk to life, however, left untreated it may progress to a life-threatening condition. Current clinico-pathological features cannot accurately predict which patients with DCIS have invasive potential, and therefore clinicians are unable to quantify the risk of progression for an individual patient.
View Article and Find Full Text PDFACS Appl Mater Interfaces
November 2021
Metal-organic frameworks (MOF) are promising media for achieving solid-state Mg conduction and developing a magnesium-based battery. To this end, the chemical behavior and transport properties of an Mg(TFSI)/DME electrolyte system inside Mg-MOF-74 were studied by density functional theory (DFT). We found that inside the MOF chemical environment, solvent and anion molecules occupy the coordinatively unsaturated open metal sites of Mg-MOF-74, while Mg ions adsorb directly onto the carboxylate group of the MOF organic linker.
View Article and Find Full Text PDFBackground: Coronavirus disease 2019 (COVID-19) has rapidly evolved into a global pandemic. The public health systems have consequently been placed under tremendous pressure. Peripherally inserted central catheters (PICCs) are widely used in patients with cancers.
View Article and Find Full Text PDFAlthough a variety of nanoparticles with better-than-bulk material performances can be synthesized, it remains a challenge to scale the extraordinary properties of individual nanoscale units to the macroscopic level for bulk nanostructured materials. Here, we report a general and scalable biosynthesis strategy that involves simultaneous growth of cellulose nanofibrils through microbial fermentation and co-deposition of various kinds of nanoscale building blocks (NBBs) through aerosol feeding on solid culture substrates. We employ this biosynthesis strategy to assemble a wide range of NBBs into cellulose nanofibril-based bulk nanocomposites.
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