Prepared chiral nanorods of a cobalt(II) porphyrin dimer and studied changes of UV-Vis and CD spectra with aggregate morphologies under different temperatures.

Novel porphyrin dimer ligand and cobalt complexes by directly bridging with l-glutamic acid have been prepared and characterized. The intensities of circular dichroism and UV-vis spectra that change the aggregate morphologies of the porphyrin dimer under different temperatures have been investigated.

[Preparation and structural characterization of ZnTHPP/TiO2 hybrid material].

Using sol-gel method to make tetra-meso (hydroxylphenyl) zinc porphyrin (ZnTHPP) trapped in inorganic networks of TiO2, a new organic/inorganic hybrid material was prepared. The structures and morphology of this material were characterized by thermogravimetric analyses (TGA), infrared spectrum (FTIR), UV-Vis spectrum (UV), diffuse reflectance spectroscopy (DRS), and scanning electron microscopy (SEM), indicating that ZnTHPP/TiO2 hybrid material possessed excellent thermostability, and ZnTHPP was trapped in TiO2 network with chemical bonds. In addition, ZnTHPP embedding can enlarge the absorption range of light for TiO2 effectivelly.