Scientific evaluation of the effectiveness of ecological restoration could provide support for sustainable management and protection of wetlands. However, due to the multiple and difficult to quantify factors affecting wetlands, commonly used spatiotemporal evaluation methods were difficult to scientifically reflect the actual effectiveness of ecological restoration. This paper took Tianjin Qilihai Wetland, a representative wetland in northern China, as the research object.
View Article and Find Full Text PDFMacromol Rapid Commun
January 2025
As a recent focal point of research, soft electronics encompass various factors that synergistically enhance their mechanical properties and ensure stable electrical performance. However, challenges such as immiscible conductive fillers, poor phase interfaces, and unstable conductive networks hinder the overall efficacy of these materials. To address these issues, a hydrogel featuring an oriented interpenetrating network structure (OIPN) is developed.
View Article and Find Full Text PDFIn this paper, we present the demonstration of a cavity-dumped Kerr-lens mode-locked femtosecond oscillator based on an Yb:CALYO crystal for the first time. With the assistance of an SESAM, the Kerr-lens mode-locked Yb:CALYO laser delivered pulses with an average power of 2.8 W at a repetition rate of 61.
View Article and Find Full Text PDFThe uranyl ion (UO) is the most stable form of uranium, which exhibits high toxicity and bioavailability posing a severe risk to human health. The construction of ultrasensitive, reliable, and robust sensing techniques for UO detection in water and soil samples remains a challenge. Herein, a DNA network biosensor was fabricated for UO detection using DNAzyme as the heavy metal recognition element and double-loop hairpin probes as DNA assembly materials.
View Article and Find Full Text PDFMagnetite is a reductive Fe(II)-bearing mineral, and its reduction property is considered important for degradation of contaminants in groundwater and anaerobic subsurface environments. However, the redox condition of subsurface environments frequently changes from anaerobic to aerobic owing to natural and anthropogenic disturbances, generating reactive oxygen species (ROS) from the interaction between Fe(II)-bearing minerals and O. Despite this, the mechanism of ROS generation induced by magnetite under aerobic conditions is poorly understood, which may play a crucial role in As(III) oxidation.
View Article and Find Full Text PDFDissimilatory arsenate reduction contributes a large proportion of arsenic flux from flooded paddy soil, which is closely linked to soil organic carbon input and efflux. Humic acid (HA) represents a natural ingredient in soil and is shown to enhance microbial arsenate respiration to promote arsenic mobility. However, the community and function profiles of metabolically active arsenate-respiring bacteria and their interactions with HA in paddy soil remain unclear.
View Article and Find Full Text PDFThe available heavy metals in soil samples can cause the direct toxicity on ecosystems, plants, and human health. Traditional chemical extraction and recombinant bacterial methods for the available heavy metals assay often suffer from inaccuracy and poor specificity. In this work, we construct half adder and half subtractor molecular logic gates with molecular-level biocomputation capabilities for the intelligent sensing of the available lead (Pb) and cadmium (Cd).
View Article and Find Full Text PDFVehicle emissions have become one of the most important air pollution sources in China. Promoting vehicle synergistic reduction of pollution and carbon is the key to improving regional environmental quality and achieving the carbon peaking and carbon neutrality goals. Building a collaborative evaluation system and comprehensive quantitative method is an important prerequisite for scientific and effective implementation of vehicle pollution and carbon synergistic reduction.
View Article and Find Full Text PDFWorld J Gastrointest Surg
November 2023
Background: Epidemiological studies have found that unconjugated bilirubin (UCB) levels are positively correlated with the incidence of colorectal cancer (CRC). Therefore, bilirubin may also play an important role in the prognosis of CRC.
Aim: To investigate the predictive value of total bilirubin (TBIL) and UCB in the prognosis of patients with CRC.
Most microaerophilic Fe(II)-oxidizing bacteria (mFeOB) belonging to the family Gallionellaceae are autotrophic microorganisms that can use inorganic carbon to drive carbon sequestration in wetlands. However, the relationship between microorganisms involved in Fe and C cycling is not well understood. Here, soil samples were collected from different wetlands to explore the distribution and correlation of Gallionella-related mFeOB and carbon-fixing microorganisms containing cbbL and cbbM genes.
View Article and Find Full Text PDFBackground: Although end-of-life care (EOLC) has been well-studied, the experience of neonatal intensive care unit (NICU) nurses in China, where little EOLC training is provided, requires further investigation.
Purpose: To explore the lived experience of EOLC delivery among NICU nurses, to provide evidence to enhance nurses' EOLC skills and improve their overall quality.
Methods: This qualitative study adopted a phenomenological approach.
Floating iron (Fe) films are widely found in wetlands that can form oxic-anoxic boundaries under circumneutral conditions. These films play a crucial role in the redox transformations and bioavailability of nutrients and trace metals. Current studies mainly focus on chemical oxidation during Fe film formation under circumneutral conditions.
View Article and Find Full Text PDFFor the surface sediment samples of Taihu Lake in 2010, the eight physicochemical indices of pH, temperature, Eh, water content, porosity, grain size, total phosphorus, and Loss-on-ignition were measured and analyzed, along with the contents of nine heavy metals:Cu, Zn, Ni, Cr, Pb, Ba, Mn, Co, and V. The order of magnitudes of heavy metal content of surface sediments in Taihu Lake was:Mn>Ba>Zn>Cr>V>Ni>Pb>Cu>Co. This suggested that the contents of the nine heavy metals were beyond the background value, which had a close connection to the geology of the Taihu Lake Basin and were influenced by human activity to varying degrees.
View Article and Find Full Text PDFA fluorescence biosensor was developed for the ultrasensitive detection of the available lead in soil samples by coupling with DNAzyme and hairpin DNA cyclic assembly. The biorecognition between lead and 8-17 DNAzyme will cleave the substrate strands (DNA2) and release the trigger DNA (T), which can be used to initiate the DNA assembly reactions among the hairpins (H1, H2, and H3). The formed Y-shaped sensing scaffold (H1-H2-H3) contains active Mg-DNAyzmes at three directions.
View Article and Find Full Text PDFThe use of the phenoxy herbicide 2,4-dichlorophenoxyacetic acid (2,4-D) has been steadily increasing in recent years due to its selectivity against broad-leafed weeds and use on genetically modified crops resistant to 2,4-D. This increases the likelihood of 2,4-D persisting in agriculturally impacted soils, sediments, and aquatic systems. Aerobic microorganisms are capable of degrading 2,4-D enzymatically.
View Article and Find Full Text PDFMacromol Rapid Commun
November 2023
The development of high-temperature resistant dielectrics with excellent dielectric properties and self-healing behavior is crucial for the application of metallized film capacitors. In this work, a series of polyetherimide (PEI) dielectric films are designed and fabricated. The introduction of polar groups is in favor to the increase of permittivity, and the flexible connection such as the ether group will facilitate the reduction of dielectric loss.
View Article and Find Full Text PDFCd speciation in soil and its transport to rice roots are influenced by the soil pH, oxidation-reduction potential, and mineral transformation; however, the immobilization and migration of Cd in soil-rice systems with different pH values under distinct water regimes remain unclear. This study used Cd isotope fractionation, soil physical analysis, and root gene quantification to elucidate the immobilization and transport of Cd in different soil-rice systems. In drainage soils, the high soil pH enhanced the transformation and magnitude of negative fractionation of Cd from MgCl extract to FeMn oxide-bound pool; however, it favored Cd uptake and root-to-grain transport.
View Article and Find Full Text PDFBiosens Bioelectron
October 2023
Understanding the sources and characteristics of PM-bound PAHs from traffic-related pollution can provide valuable data for mitigating air contamination from traffic in local urban regions. However, little information on PAHs is available regarding the typical arterial highway-Qinling Mountains No.1 tunnel in Xi'an.
View Article and Find Full Text PDFCadmium (Cd) contamination of soils is a global problem, particularly in paddy soils. Fe oxides, as a key fraction of paddy soils, can significantly affect the environmental behavior of Cd, which is controlled by complicated environmental factors. Therefore, it is necessary to systematically collect and generalize relevant knowledge, which can provide more insight into the migration mechanism of Cd and a theoretical basis for future remediation of Cd contaminated paddy soils.
View Article and Find Full Text PDFJASA Express Lett
May 2023
Performance of Doppler sonar is degraded by beam cross coupling errors. This performance degradation presents itself as the loss of precision and bias of velocity estimates output by the system. A model is proposed here to reveal the physical essence of the beam cross coupling.
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