Pauli String Partitioning Algorithm with the Ising Model for Simultaneous Measurements.

We propose an efficient algorithm for partitioning Pauli strings into subgroups, which can be simultaneously measured in a single quantum circuit. Our partitioning algorithm drastically reduces the total number of measurements in a variational quantum eigensolver for a quantum chemistry, one of the most promising applications of quantum computing. The algorithm is based on the Ising model optimization problem, which can be quickly solved using an Ising machine.

Low-Voltage, CMOS-Free Synaptic Memory Based on LiTiO Redox Transistors.

Neuromorphic computers based on analogue neural networks aim to substantially lower computing power by reducing the need to shuttle data between memory and logic units. Artificial synapses containing nonvolatile analogue conductance states enable direct computation using memory elements; however, most nonvolatile analogue memories require high write voltages and large current densities and are accompanied by nonlinear and unpredictable weight updates. Here, we develop an inorganic redox transistor based on electrochemical lithium-ion insertion into LiTiO that displays linear weight updates at both low current densities and low write voltages.

Terminal redox-site effect on the long-range electron conduction of Fe(tpy)2 oligomer wires on a gold electrode.

This article completes our comprehensive understanding of the electron transport properties of our original π-conjugated redox-active molecular wires comprising Fe bridged by p-phenylene linkers (tpy=2,2':6',2''-terpyridine). The Fe(tpy)2 oligomer wires comprise three types of tpy ligands: the anchor tpy ligand (A series) makes a junction between the wire and electrode, the bridging bis-tpy ligand (L series) connects the Fe(tpy)2 units, and the terminal tpy ligand (T series) possesses a redox site as a probe for the long-range electron transport ability. Taking advantage of the precise tunability of the composition of the Fe(tpy)2 oligomer wires, thus far we investigated how A and L impacted on the electron-transport ability.

Surface junction effects on the electron conduction of molecular wires.

Surface junction effects on the electron conduction of p-phenylene-bridged bis(terpyridine)iron oligomers terminated with a ferrocene moiety were quantitatively analyzed by employing three different surface-anchoring terpyridine ligands. The dependence of the electron-transfer rate constant for oxidation of the ferrocene moiety, k(et), on the distance between the electrode surface and the ferrocene moiety, x, showed that the attenuation factor, beta(d), which indicates the degree of reduction of k(et) with x, was approximately 0.018 in all cases.

Superior electron-transport ability of pi-conjugated redox molecular wires prepared by the stepwise coordination method on a surface.

Electronic conductivity of molecular wires is a critical fundamental issue in molecular electronics. pi-Conjugated redox molecular wires with the superior long-range electron-transport ability could be constructed on a gold surface through the stepwise ligand-metal coordination method. The beta(d) value, indicating the degree of decrease in the electron-transfer rate constant with distance along the molecular wire between the electrode and the redox active species at the terminal of the wire, were 0.