Broadband silicon nitride integrated polarization rotators at 780 nm.

Polarization management, and in particular polarization rotation, is becoming increasingly important for photonic integrated circuits (PICs). While fiber-optic networks are generally polarization insensitive, the large aspect ratio of high-index-contrast PIC waveguides leads to a large polarization-dependent response of integrated components such as waveguides, optical cavities, couplers, etc. Although foundry-processed polarization rotators operating at telecom and datacom wavelengths (C- and O-band) have been demonstrated, to date, there have been few reports of devices operating at shorter wavelengths.

Broadband near-infrared emission in silicon waveguides.

Silicon photonic integrated circuit foundries enable wafer-level fabrication of entire electro-optic systems-on-a-chip for applications ranging from datacommunication to lidar to chemical sensing. However, silicon's indirect bandgap has so far prevented its use as an on-chip optical source for these systems. Here, we describe a fullyintegrated broadband silicon waveguide light source fabricated in a state-of-the-art 300-mm foundry.

Foundry-based waveguide-enhanced Raman spectroscopy in the visible.

Waveguide-enhanced Raman spectroscopy (WERS) is an analytical technique frequently employed for chemical and biological sensing. Operation at visible wavelengths to harness the inverse fourth power with excitation wavelength signal scaling of Raman scattering intensity is desirable, to combat the inherent inefficiency of Raman spectroscopy. Until now, WERS demonstrations in the visible have required custom materials and fabrication, resulting in high losses and low yields.

MEMS-tunable polarization management in photonic integrated circuits.

Optical fibers are generally polarization-insensitive while photonic integrated circuits (PICs) often exhibit a large polarization dependence due to the high-aspect-ratio and high-index-contrast of integrated waveguides. As PICs become more mature there is an increasing need for tunable polarization management on-chip. Although micro-electro-mechanical systems (MEMS) are increasingly finding application in PICs for optical switching and phase shifting, they have so far not found wide application for polarization management.

Micro-electro-mechanically tunable optical phase matching and mode conversion.

Mode-division multiplexing (MDM) enables a large increase in the information-carrying capacity of an optical network. Recently, chip-scale MDM devices that can switch different mode orders to different output waveguides have been demonstrated. However, an important milestone showing dynamically tunable mode-order conversion in a single compact device has so far not been reported.

Optical and geometric parameter extraction for photonic integrated circuits.

We describe an in-situ technique to characterize the material refractive indices and waveguide geometry for photonic integrated circuits over hundreds of nanometers of optical bandwidth. By combining white light spectroscopy with unbalanced Mach-Zehnder interferometers, we can simultaneously and accurately extract the core thickness, core width, core refractive index, and cladding refractive index. This information is important for the technological maturation of photonic integrated circuit foundry fabrication.

Germanium-on-silicon waveguides for long-wave integrated photonics: ring resonance and thermo-optics.

Germanium-on-silicon (GOS) represents the leading platform for foundry-based long-wave infrared photonic integrated circuits (LWIR PICs), due to its CMOS compatibility and absence of oxides. We describe ring resonance (Q-factors between 2×10 and 1×10) and thermo-optic tunability in germanium-on-silicon waveguides throughout the long-wave-infrared. The ring resonances are characterized by Q-factors and couplings that agree with measurements of propagation loss (as low as 6 dB/cm) and simulations and are enabled by broadband edge coupling (12dB/facet over a 3 dB bandwidth of over 4 microns).

Passive photonic integration of lattice filters for waveguide-enhanced Raman spectroscopy.

To perform waveguide-enhanced Raman spectroscopy (WERS) or fluorescence spectroscopy in a compact device, the optical fibers to couple the passive photonic circuit to the laser source and detector require attachment directly to the die. This necessitates the integration of edge couplers and waveguide-based filters to isolate the fiber background emission from the on-chip signal, while efficiently coupling the pump laser and detector to the input and output fibers, respectively. In this work, we experimentally demonstrate the successful integration of four-port lattice filters with sensing spirals and inverse-taper edge couplers in a passive photonic circuit.

Figure-of-Merit Characterization of Hydrogen-Bond Acidic Sorbents for Waveguide-Enhanced Raman Spectroscopy.

The optical properties of several hydrogen-bond acidic sorbent materials are evaluated in situ to assess their suitability for waveguide-enhanced Raman spectroscopy (WERS) of vapor-phase organophosphonates. A number of characteristics critical to WERS are evaluated for each sorbent: infrared absorption, Raman spectral background, and the limit of detection for a test hydrogen-bond-basic analyte (dimethyl methylphosphonate, DMMP). We describe the chemical properties of the sorbents that differentiate their optical properties for sensing.

Gas chromatography using a spin-coated stationary phase and a molded elastomer micro-channel.

Many different designs of microfabricated gas chromatography columns have recently been proposed and demonstrated. These designs either incorporate a stationary phase directly into the device which limits the versatility of the column as a separator, or require coating, which presents its own problems with determining the proper conditions for each different stationary phase a user may need. Here, we present a new approach: Uniformly spin coating a flat surface with the stationary phase and creating a column by pressing a lid, with micro-fabricated ridges, down onto the coated substrate.

Loss reduction in electromechanically tunable microring cavities.

Nanophotonic structures coupled with mechanics enable large effective index perturbation. To date, however, the relation between index tuning and induced optical loss has not been considered in detail. In this work we present an in-depth study of optical loss mechanisms in an electromechanically-tunable waveguide filter.

Waveguide-enhanced Raman spectroscopy of trace chemical warfare agent simulants.

We report the measurement of waveguide-enhanced Raman spectra from trace concentrations of four vapor-phase chemical warfare agent simulants: dimethyl methylphosphonate, diethyl methylphosphonate, trimethyl phosphate, and triethyl phosphate. The spectra are obtained using highly evanescent nanophotonic silicon nitride waveguides coated with a naturally reversible hyperbranched carbosilane sorbent polymer and exhibit extrapolated one-σ detection limits as low as 5 ppb. We use a finite-element model to explain the polarization and wavelength properties of the differential spectra.

Broadband opto-electro-mechanical effective refractive index tuning on a chip.

Photonic integrated circuits have enabled progressively active functionality in compact devices with the potential for large-scale integration. To date the lowest loss photonic circuits are achieved with silica or silicon nitride-based platforms. However, these materials generally lack reconfigurability.

Suspended photonic waveguide devices.

This article describes recent research at the U.S. Naval Research Laboratory that focuses on the use of micro- and nanomachining techniques for photonic waveguide devices.

Trace gas absorption spectroscopy using functionalized microring resonators.

We detect trace gases at parts-per-billion levels using evanescent-field absorption spectroscopy in silicon nitride microring resonators coated with a functionalized sorbent polymer. An analysis of the microring resonance line shapes enables a measurement of the differential absorption spectra for a number of vapor-phase analytes. The spectra are obtained at the near-infrared overtone of OH-stretch resonance, which provides information about the toxicity of the analyte vapor.

Mid-infrared difference-frequency generation in suspended GaAs waveguides.

We experimentally demonstrate mid-infrared difference-frequency generation in suspended 181 nm thick GaAs waveguides. Generation of the idler at wavelengths between 2800 and 3150 nm is enabled by form-birefringent phase-matching in ultrahigh index-contrast waveguides. Nonlinear mixing has a measured efficiency of 0.

Integrated waveguide-DBR microcavity opto-mechanical system.

Cavity opto-mechanics exploits optical forces acting on mechanical structures. Many opto-mechanics demonstrations either require extensive alignment of optical components for probing and measurement, which limits the number of opto-mechanical devices on-chip; or the approaches limit the ability to control the opto-mechanical parameters independently. In this work, we propose an opto-mechanical architecture incorporating a waveguide-DBR microcavity coupled to an in-plane micro-bridge resonator, enabling large-scale integration on-chip with the ability to individually tune the optical and mechanical designs.

Demonstration of a mode-conversion cavity add-drop filter.

We experimentally demonstrate a new type of add-drop filter incorporating an asymmetric Y-branch waveguide coupler and a shifted-grating mode-conversion cavity. The device relies on mode separation in the asymmetric Y-branch and wavelength-selective mode conversion upon reflection from the shifted-grating cavity. Add-drop functionality is demonstrated in a three-port integrated silicon-on-insulator device.

Waveguide micro-opto-electro-mechanical resonant chemical sensors.

We demonstrate a silicon micro-opto-electro-mechanical sensor based on mass-loading of a chemo-selective polymer coated onto a microbridge. The sensor is probed optically using an on-chip waveguide Fabry-Pérot interferometer for high resolution displacement and resonant frequency measurement. The mechanical resonator is designed with paddles to simplify chemo-selective polymer deposition and to minimize any strain effects from the polymer during analyte sorption.

Thermo-optic tuning and switching in SOI waveguide Fabry-Perot microcavities.

Compact silicon-on-insulator (SOI) waveguide thermo-optically tunable Fabry-Perot microcavities with silicon/air Bragg mirrors are demonstrated. Quality factors of Q=4,584 are measured with finesse F=82. Tuning is achieved by flowing current directly through the silicon cavity resulting in efficient thermo-optic tuning over 2 nm for less than 50 mW applied electrical power.

Add-drop filters based on mode-conversion cavities.

A new type of a resonator defined by two or more mode-converting gratings in a waveguide is proposed and analyzed. It is shown that the proposed structure can exhibit narrow resonances similar to Fabry-Perot cavities but has an advantage of being a four-port device and thus is capable of serving as an add-drop filter.

Integrated waveguide Fabry-Perot microcavities with silicon/air Bragg mirrors.

We demonstrate in-plane microfabricated Fabry-Perot cavities with cryogenically etched silicon/air distributed Bragg reflector (DBR) mirrors and integrated silicon-on-insulator rib waveguides. Several DBR configurations and cavity lengths were measured. Various devices exhibit Q=26963, FWHM=0.

Crystal structure, conformation, and absolute configuration of kanamycin A.

Kanamycin, an antibiotic complex produced by Streptomyces kanamycetius isolated from Japanese soil, was described by Okami and Umezawa as early as 1957 and consists of three components: Kanamycin A (the major component), B, and C. The disulfate salt of kanamycin A [4-O-(6-amino-6-deoxy-alpha-d-glucopyranosyl)-6-O-(3-amino-3-deoxy-alpha-d-glucopyranosyl)-2-deoxystreptamine] is a broad-spectrum antibiotic that is used to treat gonorrhea, salmonella, tuberculosis, and many other diseases. Crystals of kanamycin A monosulfate monohydrate obtained from water are triclinic, space group P1, with a=7.