Biomass waste-derived magnetic material coated with dual-dummy-template molecularly imprinted polymer for simultaneous extraction of organophosphorus and carbamate pesticides.

An eco-friendly biomass waste-derived magnetic material coated with a dual-dummy-template molecularly imprinted polymer was fabricated using aqueous ethanol as a green porogen, lower amounts of toxic compounds as template molecules, and tyrosine and tryptophan as biocompatible binary monomers. The binding characteristics and selectivity of the material toward pesticides were assessed. High adsorption capacities ranging from 150.

Molecularly imprinted polymer-coated paper for the selective extraction of organophosphorus pesticides from fruits, vegetables, and cereal grains.

Biodegradable molecularly imprinted polymer-coated paper (MIP@paper) was effectively produced by polymerization using azinphos-methyl as a template molecule, terephthalic acid as a functional monomer, ethylene glycol dimethacrylate as a cross-linker, and aqueous ethanol as a green porogenic solvent. The material was subsequently composited onto cellulose paper, which served as the natural substrate, by dip coating with the aid of chitosan and citric acid natural adhesive. The properties, such as static and dynamic adsorption, selectivity, and reusability, were assessed.

Eco-friendly fabrication of a magnetic dual-template molecularly imprinted polymer for the selective enrichment of organophosphorus pesticides for fruits and vegetables.

A magnetic dual-template molecularly imprinted polymer (DMIP) was successfully prepared in an aqueous medium and used as a sorbent for the selective extraction of organophosphorus pesticides prior to analysis by high-performance liquid chromatography (HPLC). The binding properties and selectivity of DMIP toward organophosphorus were evaluated and compared with those of a non-imprinted polymer. The established magnetic dispersive solid-phase extraction (MDSPE) method using DMIP exhibited fast enrichment of the target analytes within 60 s for adsorption and 30 s for desorption.

Prevalence of per- and polyfluoroalkyl substances (PFASs) in drinking and source water from two Asian countries.

The present study focuses on the determination of the occurrence and levels of per- and polyfluoroalkyl substances (PFASs) in the drinking and source water from the Philippines and Thailand. A total of 46 samples (18 commercial bottled waters, 5 drinking water from vending machine (re-fill stations) and 23 source water) were analyzed using liquid chromatography with tandem high-resolution mass spectrometry. Using the targeted method, 12 different PFASs were detected in the drinking water samples with total quantifiable PFASs (∑PFASs) levels ranging from 7.

Simple magnetization of Fe O /MIL-53(Al)-NH for a rapid vortex-assisted dispersive magnetic solid-phase extraction of phenol residues in water samples.

The present work describes a simple route to magnetize MIL-53(Al)-NH sorbent for rapid extraction of phenol residues from environmental samples. To extend the applications and performances of the metal-organic frameworks in the field of adsorption materials, we combined the properties of metal-organic frameworks and magnetite to decrease the extraction time and simplify the extraction process as well. In this study, a simple and quick vortex-assisted dispersive magnetic solid phase extraction method for the extraction of ten United States Environmental Protection Agency's priority phenols from water samples prior to analysis by high-performance liquid chromatography with photodiode array detection was proposed.

Evaluation of metal-organic framework NH-MIL-101(Fe) as an efficient sorbent for dispersive micro-solid phase extraction of phenolic pollutants in environmental water samples.

This work proposes an application of amine-functionalized metal-organic framework (NH-MIL-101(Fe)) as sorbent for dispersive micro-solid phase extraction (D-μSPE) of ten priority phenolic pollutants. The sorbent was simply synthesized under facile condition. The entire D-μSPE process was optimized by studying the effect of experimental parameters affecting the extraction recovery of the target analytes.