Converting biomass waste into hydrogen energy through gasification is a crucial pathway for producing "green hydrogen". In a fixed bed reactor, a representative biomass waste, rice straw (RS), was pyrolyzed at N, HO, CO, and O atmospheres to generate hydrogen. Solid C-13 Nuclear Magnetic Resonance Spectroscopy (C-NMR) and Fourier Transform infrared spectroscopy (FTIR) were employed to elucidate the carbon structure and functional groups of the samples.
View Article and Find Full Text PDFIn view of the food waste (FW) as well as its digestate are both the organic sources of municipal solid waste, this study explored the anaerobic fermentation (AF) and following pyrolysis carbonization to co-disposal the two wastes for carbon resource recovery, including short chain organic acid (SCOAs), pyrolysis gas and biochar. Results indicated that both the rate and yield of SCOAs production both increase with the rising ratio of biogas sludge (BS) to FW, enhancing the soluble carbon recovery. The highest SCOAs production of 474.
View Article and Find Full Text PDFPorous carbon holds great potential for application in supercapacitors due to its rich pore structure and high specific surface area. In this research, lignin served as the starting material for the production of lignin-derived carbon materials via a carbonization-activation process. The resulting porous carbon materials underwent rigorous characterization using SEM, BET, Raman, XRD, and XPS to uncover their morphological and structural intricacies.
View Article and Find Full Text PDFPlastic waste's dual characteristics of "resource" and "pollution" led to the prevalence of trade. The Global Plastic Waste Trade Network (GPWTN) is heterogeneous, and its structure is susceptible to the influence of key countries within it. However, there is a shortage of research on the key countries and trade drivers influencing GPWTN evolution.
View Article and Find Full Text PDFUtilizing lignin-derived activated carbon in supercapacitors has emerged as a promising approach to alleviating environmental pollution and promoting the high-value utilization of byproducts in the papermaking industry. In this study, activated carbons (LACs) were prepared using a simple one-step KOH activation approach and by employing enzymatic hydrolysis lignin (EHL). The impact of the KOH activation parameters on the microstructure and capacitive performance of the LACs was investigated by varying the KOH/EHL ratio and activation temperature.
View Article and Find Full Text PDFMaterials (Basel)
September 2024
In this study, corncob was explored as a low-cost and abundant precursor for the preparation of activated carbon via carbonization and the KOH activation method. The alkaline/biochar ratios varied from 3:1 to 5:1, and the activation temperatures ranged from 700 to 900 °C. The characterized results reveal that the alkaline/biochar ratios and activation temperatures had a remarkable influence on the morphology and microstructure of as-prepared activated carbon (CAC).
View Article and Find Full Text PDFMonolithic electrocatalysts are desired for the electro-Fenton oxidation system. We used a hydrogel consisting of TEMPO-oxidized cellulose nanofibers (TOCN) and cationic guar gum (CGG) to disperse and support Fe-rich sludge and finally obtained a Fe-doped biochar (denoted as C-Sludge@TOCN/CGG) after the freeze-drying and carbonization. This C-Sludge@TOCN/CGG exhibited a porous structure with evenly-distributed Fe due to the inherently three-dimensional porous structure of TOCN/CGG hydrogel and the abundant carbon content.
View Article and Find Full Text PDFThe goal of this research was to investigate the effects of torrefying temperature (220, 260, and 300 °C) on the physicochemical properties, kinetics, thermodynamic parameters, and reaction processes of (AP) during the pyrolysis process. The kinetics of raw materials and torrefied biomass were studied by using three kinetic models, and the main function graph approach was employed to find the reaction mechanism. The torrefied biomass produced at temperatures of 220 °C (AP-220), 260 °C (AP-260), and 300 °C (AP-300) was thermogravimetrically analyzed at four different heating rates (5, 10, 15, and 20 °C/min).
View Article and Find Full Text PDFCurrently, the development of nonmetallic oxygen reduction reaction (ORR) catalysts based on heteroatomic-doped carbon materials is receiving increaseing attention in the field of fuel cells. Here, we used enzymolytic lignin (EL), melamine, and thiourea as carbon, nitrogen, and sulfur sources and NHCl as an activator to prepare N- and S-codoped lignin-based polyporous carbon (ELC) by one-step pyrolysis. The prepared lignin-derived biocarbon material (ELC-1-900) possessed a high specific surface area (844 m g), abundant mesoporous structure, and a large pore volume (0.
View Article and Find Full Text PDFAs a dewatering method of high moisture solid waste sludge, biodrying still faces environmental problems such as material loss and greenhouse gas emission in the process of treatment. In this study, biochar and magnesium chloride were used to explore the synergistic effect of enhancing sludge biodrying and reducing greenhouse gas emissions. The highest temperature of biodrying was raised to 68.
View Article and Find Full Text PDFAn effective strategy was demonstrated to design an electromagnetic interference (EMI) shielding paper via a facile surface treatment on paper. TEMPO-oxidized cellulose nanofibers (TOCN) were first integrated with TiCT MXene, and subsequently cast onto a filter paper with cationic guar gum (CGG) in a sequential way. TOCN and CGG generated a self-assembling hydrogel and formed a MXene-containing hydrogel film on top of the filter paper.
View Article and Find Full Text PDFVolatile organic compounds (VOCs) evolved from biomass gasification plays a positive role in the formation of PM and odor pollution. In order to improve the removal rate of various VOCs produced by biomass gasification, a nickel-based supported HZSM-5 cataly st (Ni/HZSM-5 and Ni-Ca-Co/HZSM-5) was prepared by different auxiliary methods, Ni loadings, and pyrolysis temperatures. The catalytic cracking performance of Ni/HZSM-5 catalysts for different VOCs model compounds such as toluene, phenol, furan, acetic acid and cyclohexane were studied in a fixed-bed reactor.
View Article and Find Full Text PDFIt is important to clarify the distribution of pyrolysis products from lignocellulosic biomass for its thermal transformation to produce high-quality bio-oil. Influences of the reaction temperature and catalysts on the pyrolysis product distribution from aspen wood (AW) and rice husk (RH) were studied by pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS). The difference in components from the lignocellulosic biomass results in different pyrolysis characteristics of the biomass raw materials.
View Article and Find Full Text PDFCombined pretreatment methods were assumed to further enhance photo-fermentative biohydrogen production (PFHP) from lignocellulosic biomass. For this purpose, an ultrasonication assisted ionic liquid pretreatment was applied to Arundo donax L. biomass for PFHP.
View Article and Find Full Text PDFInt J Environ Res Public Health
March 2023
Lignin is an ideal carbon source material, and lignin-based carbon materials have been widely used in electrochemical energy storage, catalysis, and other fields. To investigate the effects of different lignin sources on the performance of electrocatalytic oxygen reduction, different lignin-based nitrogen-doped porous carbon catalysts were prepared using enzymolytic lignin (EL), alkaline lignin (AL) and dealkaline lignin (DL) as carbon sources and melamine as a nitrogen source. The surface functional groups and thermal degradation properties of the three lignin samples were characterized, and the specific surface area, pore distribution, crystal structure, defect degree, N content, and configuration of the prepared carbon-based catalysts were also analyzed.
View Article and Find Full Text PDFIn recent years, nanocellulose-based bioinorganic nanohybrids have been exploited in numerous applications due to their unique nanostructure, excellent catalytic properties, and good biocompatibility. To the best of our knowledge, this is the first report on the simple and effective synthesis of graphene/cellulose (RGO/CNC) matrix-supported platinum nanoparticles (Pt NPs) for nonenzymatic electrochemical glucose sensing. The Pt/RGO/CNC nanohybrid presented a porous network structure, in which Pt NPs, RGO, and CNCs were integrated well.
View Article and Find Full Text PDFIn this study, Baoqing lignite (BL) and rice straw (RS), which were the representatives of low-rank coal and biomass, were co-thermally oxidized to produce composite humic substances (HS), including humic acid (HA) and fulvic acid (FA). Taking HS content as the output response, the co-thermally oxidizing conditions were optimized through single factor experiment and response surface methodology (RSM). The structures of HA and FA prepared under optimized conditions were analyzed by SEM, UV, and FTIR.
View Article and Find Full Text PDFInt J Environ Res Public Health
December 2022
Fast pyrolysis of microcrystalline cellulose (MC) was carried out by pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS). The effects of temperature, time, and a catalyst on the distribution of the pyrolysis products were analyzed. The reaction temperature and time can significantly affect the types and yields of compounds produced by cellulose pyrolysis.
View Article and Find Full Text PDFInt J Environ Res Public Health
December 2022
Torrefaction is an effective method for upgrading biomass. Cedar torrefaction is carried out in a fixed bed reactor at the temperature of 200-300 °C. The structural parameters are obtained from elemental analysis and C nuclear magnetic resonance (NMR).
View Article and Find Full Text PDFInt J Environ Res Public Health
November 2022
Replacing fossil fuels with bioenergy is crucial to achieving sustainable development and carbon neutrality. To determine the priorities and developing trends of bioenergy technology, related publications from 2000 to 2020 were analyzed using bibliometric method. Results demonstrated that the number of publications on bioenergy increased rapidly since 2005, and the average growth rate from 2005 to 2011 reached a maximum of 20% per year.
View Article and Find Full Text PDFSubstances harmful to photo-fermentative biological hydrogen production (PFHP) were produced during cellulose hydrolysis. This study aimed to evaluate the effect of by-products (5-hydroxymethylfurfural (5-HMF) and furfural) released from lignocellulose during enzymatic hydrolysis process on PFHP. The exist of 5-HMF inhibited the hydrogen production.
View Article and Find Full Text PDFSuitable illumination project would help in achieving high light conversion efficiency (LCE) for photo-fermentation. This study proposed an improvement strategy for LCE of photo-fermentative hydrogen production (PFHP) with a photosynthetic consortium by adopting light-dark duration alternation. For this purpose, 6 projects (continues light, 24 h light + 24 h dark, 24 h dark + 24 h light, 48 h light + 48 h light, 48 h dark + 48 h light, and continues dark) light disturbances were carried out to estimate the strategy.
View Article and Find Full Text PDFIonic liquids (ILs) pretreatment has been regarded as a promising green way to treat lignocellulosic biomass. 1-Butyl-3-methylimidazolium tetrafluoroborate ([Bmim]BF), 1-allyl-3-methylimidazolium chloride ([Amim]Cl), and 1-Butyl-3-methylimidazolium Hydrogen Sulfate ([Bmim]HSO) with different loadings (2, 4, 8, and 16 g/L) were adopted to pretreat the Arundo donax L..
View Article and Find Full Text PDFCarbon-alumina composites are prepared for the efficient removal of Cr(VI) from wastewater. Pristine and acid-treated alumina dross (AD and AAD) are copyrolyzed with pine sawdust to form the respective composites, ADPC and AADPC. Excellent absorption properties with Cr(VI) removal efficiency of 95.
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