Kinetic and isotherm studies on the adsorption of ionic liquids from aqueous solutions by carboxymethyl cellulose modified with sodium methacrylate sulfonate.

A novel carboxymethyl cellulose (CMC) graft copolymer (CMC-g-PSMAS) was successfully synthesized by grafting sodium methacrylate sulfonate (SMAS) onto CMC. The resulting CMC-g-PSMAS was used to absorb 1-allyl-3-methylimidazole chloride ([Amim]Cl) ionic liquid. The effects of different experimental factors such as monomer dosage, temperature and time on the grafting yield were systematically studied.

Mechanically Excellent, Notch-Insensitive, and Highly Conductive Double-Network Hydrogel for Flexible Strain Sensor.

A novel double-network conductive hydrogel based on lithium acetate/gelatin/polyacrylamide (PAAM) was synthesized by heating-cooling and subsequent γ-ray radiation-induced polymerization and cross-linking. Owing to the hydrogen bonding interaction between lithium acetate, physical cross-linked gelatin, and chemical cross-linked PAAM, the resultant hydrogel exhibited high tensile strength (1260 kPa), high ionic conductivity (35.2 mS cm), notch-insensitivity (tensile strength 415 kPa, elongation at break 872% with transverse notch), and extensive strain monitoring range (0.

Mechanically Robust and Highly Conductive Poly(ionic liquid)/Polyacrylamide Double-Network Hydrogel Electrolytes for Flexible Symmetric Supercapacitors with a Wide Operating Voltage Range.

Flexible electronic devices, such as supercapacitors (SCs), place high demands on the mechanical properties, ionic conductivity, and electrochemical stability of electrolytes. Hydrogels, which combine flexibility and the advantages of both solid and liquid electrolytes, will meet the demand. Here, we report the synthesis of novel poly(ionic liquid)/polyacrylamide double-network (DN) (PIL/PAM DN) hydrogel electrolytes containing different metal salts via a two-step γ-radiation method.

Synthesis and property of superabsorbent polymer based on cellulose grafted 2-acrylamido-2-methyl-1-propanesulfonic acid.

An eco-friendly superabsorbent polymer (SAP) was prepared by grafting 2-acrylamido-2-methyl-1-propanesulfonic acid onto microcrystalline cellulose in lithium chloride/N, N-dimethylacetamide system. The synthesized SAP (cellulose-g-PAMPS) was characterized by FTIR, TGA, SEM, H NMR, C NMR and XRD. The water absorption equilibrium of cellulose-g-PAMPS could be achieved within 10 min in distilled water.

Ultrastretchable and adhesive agarose/TiCT-crosslinked-polyacrylamide double-network hydrogel for strain sensor.

A novel agarose/TiCT-crosslinked-polyacrylamide (AG/T-PAM) double-network (DN) hydrogel is synthesized by combining heating-cooling and γ-ray radiation-induced polymerization. The AG/T-PAM DN hydrogel possesses excellent mechanical properties with 4250% stretchability, and good adhesion to different substrates, such as an adhesive strength of 1148 kPa to copper at 30 °C. The resultant hydrogel also exhibits excellent tensile and compression sensing properties due to the variation of conductive network within hydrogel.

Polyacrylamide/Copper-Alginate Double Network Hydrogel Electrolyte with Excellent Mechanical Properties and Strain-Sensitivity.

The double network (DN) hydrogel has attracted great attention due to its wide applications in daily life. However, synthesis DN hydrogel with excellent mechanical properties is still a big challenge. Here, polyacrylamide/copper-alginate double network (PAM/Cu-alg DN) hydrogel electrolyte is successfully synthesized by radiation-induced polymerization and cross-linking process of acrylamide with N, N'-methylene-bis-acrylamide and subsequent cupric ion (Cu ) crosslinking of alginate.

One-step radiation synthesis of agarose/polyacrylamide double-network hydrogel with extremely excellent mechanical properties.

A facile one-step radiation method is first developed to synthesize agarose/polyacrylamide (AG/PAM) double-network (DN) hydrogel. Compared to other synthetic methods of DN hydrogels, our synthesis method endows the resultant AG/PAM DN hydrogel with not only top-level tensile properties with a tensile strength of 1263 ± 59 kPa and an elongation at break of 3406 ± 143%, but also highest compression properties with a compression strength of 140 ± 3 MPa and a fracture compression strain of above 99.9%.

One-Pot Synthesis of a Double-Network Hydrogel Electrolyte with Extraordinarily Excellent Mechanical Properties for a Highly Compressible and Bendable Flexible Supercapacitor.

High-performance hydrogel electrolytes play a crucial role in flexible supercapacitors (SCs). However, the unsatisfactory mechanical properties of widely used polyvinyl alcohol-based electrolytes greatly limit their use in the flexible SCs. Here, a novel LiSO-containing agarose/polyacrylamide double-network (Li-AG/PAM DN) hydrogel electrolyte was synthesized by a heating-cooling and subsequent radiation-induced polymerization and cross-linking process.