Identification of synergistic Cu/V redox pair in VCu:AlPO-5; a comparison with VCu:ZSM-5.

Vanadium(V) and copper(II) were co-deposited into AlPO-5 and H-ZSM-5 three-dimensional microporous carriers to yield VCu:AlPO-5 and VCu:ZSM-5. The materials, along with copper analogues were tested for the selective oxidation of propene, and the catalysts perform in the following order: VCu:AlPO-5 > Cu:AlPO-5 > VCu:ZSM-5 > Cu:ZSM-5. Acrolein was selectively formed over VCu:AlPO-5 and Cu:AlPO-5 over a very wide range from 300 to 450 °C, whereas VCu:ZSM-5 displays a limited temperature window for acrolein formation (300-350 °C).