Photoassociation of ultracold NaLi.

We perform photoassociation spectroscopy in an ultracold Na-Li mixture to study the cΣ excited triplet molecular potential. We observe 50 vibrational states and their substructure to an accuracy of 20 MHz, and provide line strength data from photoassociation loss measurements. An analysis of the vibrational line positions using near-dissociation expansions and a full potential fit is presented.

Two-photon spectroscopy of the NaLi triplet ground state.

We employ two-photon spectroscopy to study the vibrational states of the triplet ground state potential (aΣ) of the NaLi molecule. Pairs of Na and Li atoms in an ultracold mixture are photoassociated into an excited triplet molecular state, which in turn is coupled to vibrational states of the triplet ground potential. Vibrational state binding energies, line strengths, and potential fitting parameters for the triplet ground aΣ potential are reported.

Long-Lived Ultracold Molecules with Electric and Magnetic Dipole Moments.

We create fermionic dipolar ^{23}Na^{6}Li molecules in their triplet ground state from an ultracold mixture of ^{23}Na and ^{6}Li. Using magnetoassociation across a narrow Feshbach resonance followed by a two-photon stimulated Raman adiabatic passage to the triplet ground state, we produce 3×10^{4} ground state molecules in a spin-polarized state. We observe a lifetime of 4.

Deviation from universality in collisions of ultracold 6Li2 molecules.

Collisions of 6Li2 molecules with free 6Li atoms reveal a striking deviation from universal predictions based on long-range van der Waals interactions. Li2 closed-channel molecules are formed in the highest vibrational state near a narrow Feshbach resonance and decay via two-body collisions with Li2, Li, and Na. For Li2 + Li2 and Li2 + Na, the decay rates agree with the universal predictions of the quantum Langevin model.