Quantum scattering of icosahedron fullerene C with noble-gas atoms.

There exist multiple ways to cool neutral molecules. A front runner is the technique of buffer gas cooling, where momentum-changing collisions with abundant cold noble-gas atoms cool the molecules. This approach can, in principle, produce the most diverse samples of cold molecules.

Quantum Control of Atom-Ion Charge Exchange via Light-Induced Conical Intersections.

Conical intersections are crossing points or lines between two or more adiabatic electronic potential energy surfaces in the multidimensional coordinate space of colliding atoms and molecules. Conical intersections and corresponding nonadiabatic coupling can greatly affect molecular dynamics and chemical properties. In this paper, we predict significant or measurable nonadiabatic effects in an ultracold atom-ion charge-exchange reaction in the presence of laser-induced conical intersections (LICIs).

Elastic and glancing-angle rate coefficients for heating of ultracold Li and Rb atoms by collisions with room-temperature noble gases, H, and N.

Trapped ultracold alkali-metal atoms can be used to measure pressure in the ultra-high-vacuum and XHV pressure regimes, those with p < 10 Pa. This application for ultracold atoms relies on precise knowledge of collision rate coefficients of alkali-metal atoms with residual room-temperature atoms and molecules in the ambient vacuum or with deliberately introduced gasses. Here, we determine combined elastic and inelastic rate coefficients as well as glancing-angle rate coefficients for ultracold Li and Rb with room-temperature noble gas atoms as well as H and N molecules.

Precise quantum measurement of vacuum with cold atoms.

We describe the cold-atom vacuum standards (CAVS) under development at the National Institute of Standards and Technology (NIST). The CAVS measures pressure in the ultra-high and extreme-high vacuum regimes by measuring the loss rate of sub-millikelvin sensor atoms from a magnetic trap. Ab initio quantum scattering calculations of cross sections and rate coefficients relate the density of background gas molecules or atoms to the loss rate of ultra-cold sensor atoms.

Simplify your life.

Within the Hartree atomic unit systems, the Schrödinger equation becomes parameter free. But there's more to it than making a student's life easier, as Gordon Drake and Eite Tiesinga recount.

Roaming pathways and survival probability in real-time collisional dynamics of cold and controlled bialkali molecules.

Perfectly controlled molecules are at the forefront of the quest to explore chemical reactivity at ultra low temperatures. Here, we investigate for the first time the formation of the long-lived intermediates in the time-dependent scattering of cold bialkali [Formula: see text]Rb molecules with and without the presence of infrared trapping light. During the nearly 50 nanoseconds mean collision time of the intermediate complex, we observe unconventional roaming when for a few tens of picoseconds either NaRb or [Formula: see text] and [Formula: see text] molecules with large relative separation are formed before returning to the four-atom complex.

CODATA Recommended Values of the Fundamental Physical Constants: 2018.

We report the 2018 self-consistent values of constants and conversion factors of physics and chemistry recommended by the Committee on Data of the International Science Council. The recommended values can also be found at physics.nist.

CODATA recommended values of the fundamental physical constants: 2018.

We report the 2018 self-consistent values of constants and conversion factors of physics and chemistry recommended by the Committee on Data of the International Science Council (CODATA). The recommended values can also be found at physics.nist.

Collisions of room-temperature helium with ultracold lithium and the van der Waals bound state of HeLi.

We have computed the thermally averaged total, elastic rate coefficient for the collision of a room-temperature helium atom with an ultracold lithium atom. This rate coefficient has been computed as part of the characterization of a cold-atom vacuum sensor based on laser-cooled Li or Li atoms that will operate in the ultrahigh-vacuum ( < 10 Pa) and extreme-high-vacuum ( < 10 Pa) regimes. The analysis involves computing the Σ HeLi Born-Oppenheimer potential followed by the numerical solution of the relevant radial Schrodinger equation.

Feshbach Resonances in -Wave Three-Body Recombination within Fermi-Fermi Mixtures of Open-Shell Li and Closed-Shell Yb Atoms.

We report on the observation of magnetic Feshbach resonances in a Fermi-Fermi mixture of ultracold atoms with extreme mass imbalance and on their unique -wave dominated three-body recombination processes. Our system consists of open-shell alkali-metal Li and closed-shell Yb atoms, both spin polarized and held at various temperatures between 1 and 20 K. We confirm that Feshbach resonances in this system are solely the result of a weak separation-dependent hyperfine coupling between the electronic spin of Li and the nuclear spin of Yb.

Elastic rate coefficients for Li+H collisions in the calibration of a cold-atom vacuum standard.

Ongoing efforts at the National Institute of Standards and Technology in creating a cold-atom vacuum standard device have prompted theoretical investigations of atom-molecule collision processes that characterize its operation. Such a device will operate as a primary standard for the ultrahigh-vacuum and extreme-high-vacuum regimes. This device operates by relating loss of ultracold lithium atoms from a conservative trap by collisions with ambient atoms and molecules to the background density and thus pressure through the ideal gas law.

A semiclassical theory of phase-space dynamics of interacting bosons.

We study the phase-space representation of dynamics of bosons in the semiclassical regime where the occupation number of the modes is large. To this end, we employ the van Vleck-Gutzwiller propagator to obtain an approximation for the Green's function of the Wigner distribution. The semiclassical analysis incorporates interference of classical paths and reduces to the truncated Wigner approximation (TWA) when the interference is ignored.

Observation of bound state self-interaction in a nano-eV atom collider.

Quantum mechanical scattering resonances for colliding particles occur when a continuum scattering state couples to a discrete bound state between them. The coupling also causes the bound state to interact with itself via the continuum and leads to a shift in the bound state energy, but, lacking knowledge of the bare bound state energy, measuring this self-energy via the resonance position has remained elusive. Here, we report on the direct observation of self-interaction by using a nano-eV atom collider to track the position of a magnetically-tunable Feshbach resonance through a parameter space spanned by energy and magnetic field.

Dispersive optical detection of magnetic Feshbach resonances in ultracold gases.

Magnetically tunable Feshbach resonances in ultracold atomic systems are chiefly identified and characterized through time-consuming atom loss spectroscopy. We describe an off-resonant dispersive optical probing technique to rapidly locate Feshbach resonances and demonstrate the method by locating four resonances of Rb, between the |F = 1,m = 1〉 and |F = 2,m = 0〉 states. Despite the loss features being ≲0.

Phase-space mixing in dynamically unstable, integrable few-mode quantum systems.

Quenches in isolated quantum systems are currently a subject of intense study. Here, we consider quantum few-mode systems that are integrable in their classical mean-field limit and become dynamically unstable after a quench of a system parameter. Specifically, we study a Bose-Einstein condensate (BEC) in a double-well potential and an antiferromagnetic spinor BEC constrained to a single spatial mode.

Pendular trapping conditions for ultracold polar molecules enforced by external electric fields.

We theoretically investigate trapping conditions for ultracold polar molecules in optical lattices, when external magnetic and electric fields are simultaneously applied. Our results are based on an accurate electronic-structure calculation of the polar NaK polar molecule in its absolute ground state combined with a calculation of its rovibrational-hyperfine motion. We find that an electric field strength of 5.

Fractal universality in near-threshold magnetic lanthanide dimers.

Ergodic quantum systems are often quite alike, whereas nonergodic, fractal systems are unique and display characteristic properties. We explore one of these fractal systems, weakly bound dysprosium lanthanide molecules, in an external magnetic field. As recently shown, colliding ultracold magnetic dysprosium atoms display a soft chaotic behavior with a small degree of disorder.

A spinor Bose-Einstein condensate phase-sensitive amplifier for SU(1,1) interferometry.

The SU(1,1) interferometer was originally conceived as a Mach-Zehnder interferometer with the beam-splitters replaced by parametric amplifiers. The parametric amplifiers produce states with correlations that result in enhanced phase sensitivity. = 1 spinor Bose-Einstein condensates (BECs) can serve as the parametric amplifiers for an atomic version of such an interferometer by collisionally producing entangled pairs of | = 1, = ±1〉 atoms.

Orbital quantum magnetism in spin dynamics of strongly interacting magnetic lanthanide atoms.

Laser-cooled lanthanide atoms are ideal candidates with which to study strong and unconventional quantum magnetism with exotic phases. Here, we use state-of-the-art closed-coupling simulations to model quantum magnetism for pairs of ultracold spin-6 erbium lanthanide atoms placed in a deep optical lattice. In contrast to the widely used single-channel Hubbard model description of atoms and molecules in an optical lattice, we focus on the single-site spin evolution due to spin-dependent contact, anisotropic van der Waals, and dipolar forces.

Challenges to miniaturizing cold atom technology for deployable vacuum metrology.

Cold atoms are excellent metrological tools; they currently realize SI time and, soon, SI pressure in the ultra-high (UHV) and extreme high vacuum (XHV) regimes. The development of primary, vacuum metrology based on cold atoms currently falls under the purview of national metrology institutes. Under the emerging paradigm of the "quantum-SI", these technologies become deployable (relatively easy-to-use sensors that integrate with other vacuum chambers), providing a primary realization of the pascal in the UHV and XHV for the end-user.

Development of a new UHV/XHV pressure standard (Cold Atom Vacuum Standard).

The National Institute of Standards and Technology has recently begun a program to develop a primary pressure standard that is based on ultra-cold atoms, covering a pressure range of 1 × 10 Pa to 1 × 10 Pa and possibly lower. These pressures correspond to the entire ultra-high vacuum (UHV) range and extend into the extreme-high vacuum (XHV). This cold-atom vacuum standard (CAVS) is both a primary standard and absolute sensor of vacuum.

Above-threshold scattering about a Feshbach resonance for ultracold atoms in an optical collider.

Ultracold atomic gases have realized numerous paradigms of condensed matter physics, where control over interactions has crucially been afforded by tunable Feshbach resonances. So far, the characterization of these Feshbach resonances has almost exclusively relied on experiments in the threshold regime near zero energy. Here, we use a laser-based collider to probe a narrow magnetic Feshbach resonance of rubidium above threshold.

Investigation of Feshbach resonances in ultracold K spin mixtures.

Magnetically tunable Feshbach resonances are an indispensable tool for experiments with atomic quantum gases. We report on 37 thus far unpublished Feshbach resonances and four further probable Feshbach resonances in spin mixtures of ultracold fermionic K with temperatures well below 100 nK. In particular, we locate a broad resonance at = 389.

Wannier functions using a discrete variable representation for optical lattices.

We propose a numerical method using the discrete variable representation (DVR) for constructing real-valued Wannier functions localized in a unit cell for both symmetric and asymmetric periodic potentials. We apply these results to finding Wannier functions for ultracold atoms trapped in laser-generated optical lattices. Following S.

Multiple scattering dynamics of fermions at an isolated p-wave resonance.

The wavefunction for indistinguishable fermions is anti-symmetric under particle exchange, which directly leads to the Pauli exclusion principle, and hence underlies the structure of atoms and the properties of almost all materials. In the dynamics of collisions between two indistinguishable fermions, this requirement strictly prohibits scattering into 90° angles. Here we experimentally investigate the collisions of ultracold clouds fermionic (40)K atoms by directly measuring scattering distributions.