Electrochemical, surface, and theoretical investigations of palm kernel shell extract as an effective inhibitor for carbon-steel corrosion in 1 M HCl solution.

Herein, we employed palm kernel shell extract (PKSE) as an eco-friendly inhibitor for carbon steel in acidic-induced corrosion. The corrosion inhibition of PKSE on carbon steel in 1 M HCI solution was investigated by electrochemical impedance spectroscopy, weight loss, and potentiodynamic polarization measurements. The surface was characterized by scanning electron microscopy equipped with energy-dispersive X-ray spectroscopy.

An overview of biochar production techniques and application in iron and steel industries.

Integrating innovation and environmental responsibility has become important in pursuing sustainable industrial practices in the contemporary world. These twin imperatives have stimulated research into developing methods that optimize industrial processes, enhancing efficiency and effectiveness while mitigating undesirable ecological impacts. This objective is exemplified by the emergence of biochar derived from the thermo-chemical transformation of biomass.

Examining the ability of palm kernel shell extract to control corrosion and assess its economic value on thermo-mechanically treated steel in artificial seawater: a sustainable and environmentally friendly approach.

Each year, the rising demand for palm oil generates large amounts of palm kernel shell waste. Discarded palm kernel shells can produce activated carbon, crushed shells, liquified fumes, and other derivatives; however, their indiscriminate disposal persists, raising issues related to the environment and economy. Therefore, the purpose of this study is to investigate the use of palm kernel shell as a corrosion inhibitor for thermo-mechanically treated steel in a seawater environment using gravimetric and electrochemical techniques, as well as surface tests at varying concentrations.

Syngas Production from CO and HO via Solid-Oxide Electrolyzer Cells: Fundamentals, Materials, Degradation, Operating Conditions, and Applications.

Highly efficient coelectrolysis of CO/HO into syngas (a mixture of CO/H), and subsequent syngas conversion to fuels and value-added chemicals, is one of the most promising alternatives to reach the corner of zero carbon strategy and renewable electricity storage. This research reviews the current state-of-the-art advancements in the coelectrolysis of CO/HO in solid oxide electrolyzer cells (SOECs) to produce the important syngas intermediate. The overviews of the latest research on the operating principles and thermodynamic and kinetic models are included for both oxygen-ion- and proton-conducting SOECs.

Adaptation of solar energy in the Global South: Prospects, challenges and opportunities.

The Global South comprising economically disadvantaged regions of the world face various challenges such as limited access to electricity, clean water, industrialization, and food security. Solar energy, as a sustainable and abundant resource, holds great potential to address these challenges. Despite its immense potential, the Global South encounters hurdles related to technology adoption, infrastructure, and financial constraints.

Investigation on electrochemical performance of striped, β12 and χ3 Borophene as anode materials for lithium-ion batteries.

By developing next-generation lithium-ion batteries (LIBS), demand for exploring novel anode materials with exclusive electrochemical features and ultra-high capacity is increasing. In the current research, first-principles theory, and density functional theory (DFT) calculations were conducted to extensively investigate and compare the capability of three different borophene nanolayers, including striped, β12, and χ3 borophene, as a novel candidate for anode electrode in LIBs. We first predicted the most preferential Li atom adsorption sites on the three borophene structures.

Performance and emission analysis of a CI engine fueled with parsley biodiesel-diesel blend.

Pollution-induced environmental deterioration is one of the serious aspects that must be solved. As a result, biodiesel was made from a novel material (Parsley seed oil) through an alkali-induced transesterification reaction. The efficiency, as well as exhaust emission tests, were performed by running the prepared parsley biodiesel blends (mixture of biodiesel and diesel fuel in different proportions) in an engine.

Continuous Fabrication of TiCT MXene-Based Braided Coaxial Zinc-Ion Hybrid Supercapacitors with Improved Performance.

TiCT MXene-based coaxial zinc-ion hybrid fiber supercapacitors (FSCs) were fabricated with braided structure, which can be prepared continuously and present excellent flexibility and ultrastability. A sports watch driven by the watch belts which weaved uses the obtained zinc-ion hybrid FSC and LED arrays lighted by the FSCs under embedding into textiles, demonstrating the great potential application in smart wearable textiles. Zinc-ion hybrid fiber supercapacitors (FSCs) are promising energy storages for wearable electronics owing to their high energy density, good flexibility, and weavability.

Yield Response from the Catalytic Conversion of Parsley Seed Oil into Biodiesel Using a Heterogeneous and Homogeneous Catalyst.

This research work is focused on the investigation of the optimum condition for parsley seed oil (PSO) trans-esterification using a heterogeneous (CCB) and homogenous catalyst (KOH). The process parameters (alcohol: oil ratio, temperature, and catalyst loading) were varied to examine their effect on the percentage biodiesel yield using a Box-Behnken design embedded with the response surface methodology (RSM). Also, the heterogeneous catalyst was synthesized by calcining waste chicken bones at 900 °C for 4 h.

Environmental impact assessment of the current, emerging, and alternative waste management systems using life cycle assessment tools: a case study of Johannesburg, South Africa.

Proper information regarding the performance of waste management systems from an environmental perspective is significant to sustainable waste management decisions and planning toward the selection of the least impactful treatment options. However, little is known about the environmental impacts of the different waste management options in South Africa. This study is therefore aimed at using the life cycle assessment tool to assess the environmental impact of the current, emerging, and alternative waste management systems in South Africa, using the city of Johannesburg as a case study.

TIG welding of Ti6Al4V alloy: Microstructure, fractography, tensile and microhardness data.

Titanium alloy is widely used in many industries due to its unique weight to strength ratio and high corrosion resistance. A suitable method of joining Titanium and its alloys is using Tungsten Inert Gas (TIG) welding. A significant advantage of TIG welding over other fusion welding is its ability to use non-consumable electrodes.

Densification of agro-residues for sustainable energy generation: an overview.

The global demand for sustainable energy is increasing due to urbanization, industrialization, population, and developmental growth. Transforming the large quantities of biomass resources such as agro-residues/wastes could raise the energy supply and promote energy mix. Residues of biomass instituted in the rural and industrial centers are enormous, and poor management of these residues results in several indescribable environmental threats.

Nanoporous MoS Membrane for Water Desalination: A Molecular Dynamics Study.

Molybdenum disulfide (MoS), a two-dimensional (2D) material, promises better desalination efficiency, benefiting from the small diffusion length. While the monolayer nanoporous MoS membrane has great potential in the reverse osmosis (RO) desalination membrane, multilayer MoS membranes are more feasible to synthesize and economical than the monolayer MoS membrane. Building on the monolayer MoS membrane knowledge, the effects of the multilayer MoS membrane in water desalination were explored, and the results showed that increasing the pore size from 3 to 6 Å resulted in higher permeability but with lower salt rejection.

Synthesis of beta-tricalcium phosphate catalyst from Herring fishbone for the transesterification of parsley seed oil.

The transesterification of parsley seed oil using a heterogeneous catalyst prepared from Herring fishbone (HFB) was investigated in this study. The fishbone was calcined at 900C for 4 h to convert the calcium phosphate in the bone to beta-tricalcium phosphate. The prepared catalyst was then characterized by employing scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD) analysis to determine its morphology and elemental composition.

Application of artificial neural networks for predicting the physical composition of municipal solid waste: An assessment of the impact of seasonal variation.

Sustainable planning of waste management is contingent on reliable data on waste characteristics and their variation across the seasons owing to the consequential environmental impact of such variation. Traditional waste characterization techniques in most developing countries are time-consuming and expensive; hence the need to address the issue from a modelling approach arises. In modelling the complexity within the system, a paradigm shift from the classical models to the intelligent models has been observed.

Prediction of municipal solid waste generation: an investigation of the effect of clustering techniques and parameters on ANFIS model performance.

The present waste-management system in most developing countries are insufficient to combat the challenge of increasing rate of solid waste generation. Accurate prediction of waste generated through modelling approach will help to overcome the challenge of deficient-planning of sustainable waste-management. In modelling the complexity within a system, a paradigm-shift from classical-model to artificial intelligent model has been necessitated.

A Molecular Dynamics Investigation of the Temperature Effect on the Mechanical Properties of Selected Thin Films for Hydrogen Separation.

In this study, we performed nanoindentation test using the molecular dynamic (MD) approach on a selected thin film of palladium, vanadium, copper and niobium coated on the vanadium substrate at a loading rate of 0.5 Å/ps. The thermosetting control is applied with temperature variance from 300 to 700 K to study the mechanical characteristics of the selected thin films.

One-Pot Synthesized Visible Light-Driven BiOCl/AgCl/BiVO n-p Heterojunction for Photocatalytic Degradation of Pharmaceutical Pollutants.

A novel enhanced visible light absorption BiOCl/AgCl/BiVO heterojunction of photocatalysts could be obtained through a one-pot hydrothermal method used with two different pH solutions. There was a relationship between synthesis pH and the ratio of BiOCl to BiVO in XRD planes and their photocatalytic activity. The visible light photocatalytic performances of photocatalysts were evaluated via degradation of diclofenac (DCFF) as a pharmaceutical model pollutant.

New development of atomic layer deposition: processes, methods and applications.

Atomic layer deposition (ALD) is an ultra-thin film deposition technique that has found many applications owing to its distinct abilities. They include uniform deposition of conformal films with controllable thickness, even on complex three-dimensional surfaces, and can improve the efficiency of electronic devices. This technology has attracted significant interest both for fundamental understanding how the new functional materials can be synthesized by ALD and for numerous practical applications, particularly in advanced nanopatterning for microelectronics, energy storage systems, desalinations, catalysis and medical fields.

Chitosan modified N, S-doped TiO and N, S-doped ZnO for visible light photocatalytic degradation of tetracycline.

N, S-doped TiO (NST), N, S-doped ZnO (NSZ) and their composite with chitosan (NST/CS, NSZ/CS) were synthesized by sol gel-hydrothermal method. The prepared samples were characterized using XRD, FTIR, TEM and BET techniques. These photocatalysts were used for the photocatalytic degradation of tetracycline under visible light irradiation.

Systematic Study of the SiO Film with Different Stoichiometry by Plasma-Enhanced Atomic Layer Deposition and Its Application in SiO/SiO₂ Super-Lattice.

Atomic scale control of the thickness of thin film makes atomic layer deposition highly advantageous in the preparation of high quality super-lattices. However, precisely controlling the film chemical stoichiometry is very challenging. In this study, we deposited SiO film with different stoichiometry by plasma enhanced atomic layer deposition.