A kinetic and mechanistic study of the self-reaction between two propargyl radicals.

Context: The propargyl radical plays a critical role in various chemical processes, including hydrocarbon combustion, flame synthesis, and interstellar chemistry. Its unique stability arises from the delocalization of π-electrons, allowing it to participate in a wide range of reactions despite being a radical. The self-reaction of propargyl radicals is a fundamental step in synthesizing polycyclic aromatic hydrocarbons.

Machine learning-based assessment of regional-scale variation of landslide susceptibility in central Vietnam.

Recurrent landslide events triggered by typhoons and tropical storms over Vietnam pose a longstanding threat to the nation's population and infrastructure. Changes in hydroclimatic conditions, especially the growing intensity and frequency of storms, have elevated landslide susceptibility in many parts of the country. This research examines the spatio-temporal variations in landslide susceptibility across central Vietnam over several years, using multi-temporal landslide inventories from Typhoon Ketsana (2009), Tropical Storm Podul (2013), and Typhoon Molave (2020).

Land use, land cover changes and expansion of artificial reservoirs in Eastern Thailand: implications for agriculture and vegetation drought reduction.

Eastern Thailand and Rayong province face perennial drought and water scarcity due to natural characteristics of climate and geology. Therefore, increasing water surface by man-made reservoirs is one of the priorities in the regional development plan to provide water adequately for industrial purposes, domestic consumption, and agriculture. The large reservoir constructions may induce land use, land cover changes (LULCC), yet it also is expected to alleviate the drought harshness in the region.

Comparing Outcomes Between Standard Mepilex and Mepilex Silver for Tracheotomy Dressings.

Objective: The purpose of the study is to compare the incidence of early postoperative tracheotomy stoma wound complications in pediatric patients using a silver-impregnated barrier dressing (Mepilex Ag) versus a standard absorbent foam dressing (standard Mepilex).

Methods: This is a prospective, non-blinded, randomized trial of pediatric patients undergoing tracheotomy at a tertiary care children's hospital. Patients were randomized to receive Mepilex Ag versus standard Mepilex tracheostoma dressings following tracheotomy.

CapNet: An Automatic Attention-Based with Mixer Model for Cardiovascular Magnetic Resonance Image Segmentation.

Deep neural networks have shown excellent performance in medical image segmentation, especially for cardiac images. Transformer-based models, though having advantages over convolutional neural networks due to the ability of long-range dependence learning, still have shortcomings such as having a large number of parameters and and high computational cost. Additionally, for better results, they are often pretrained on a larger data, thus requiring large memory size and increasing resource expenses.

Mechanistic and kinetic insights of the formation of allene and propyne from the CH reaction with water.

Context: Allene (HC = C = CH) and propyne (CH-C≡CH) are important compounds in the combustion chemistry. They can be created from the reaction of proparyl radicals with water. In this study, therefore, a computational study into the CH + HO potential energy landscape has been carefully conducted.

Highly adsorptive removal of ciprofloxacin and E. coli inactivation using amino acid tryptophan modified nano-gibbsite.

Adsorption of essential amino acid, Tryptophan (Tryp) on synthesized gibbsite nanoparticles and their applications in eliminating of antibiotic ciprofloxacin (CFX) and bacteria Escherichia coli (E. coli) in aqueous solution. Nano-gibbsite which was successfully fabricated, was characterized by XRD, TEM-SAED, FT-IR, SEM-EDX and zeta potential measurements.

Kinetics and mechanism of the gas-phase reaction of the hydroxyl radical with meta-aminotoluene compound.

Context: An ab initio investigation into the potential energy landscape of the meta-aminotoluene + OH reaction has been conducted in this study. The calculated results reveal that the reaction channel leading to the product (NHCHCH + HO) prevails under the 300-1700 K temperature range, while the reaction path forming the product (NHCHCH + HO) dominates in the higher-temperature region (T ≥ 1800 K). Within the specified temperature range, the product branching ratio for the former declines from 48 to 30%, while the latter shows an increase, reaching 29%.

Recent advances in methods for live-cell RNA imaging.

As one of the most fundamental building blocks of life, RNA plays critical roles in diverse biological processes, from X chromosome inactivation, genome stability maintenance, to embryo development. Being able to visualize the localization and dynamics of RNA can provide critical insights into these fundamental processes. In this review, we provide an overview of current methods for live-cell RNA imaging with a focus on methods for visualizing RNA in living mammalian cells with single-molecule resolution.

Apply EZStrobe to simulate the finishing work for reducing construction process waste.

Vietnam, classified as a developing nation, encounters numerous challenges within its construction sector, including the scarcity of comprehensive and documented historical data regarding risks and a deficiency in embracing contemporary methodologies to mitigate the impact of risk factors on construction project objectives. This paper outlines initial findings from an ongoing research endeavor that centers on implementing Lean Construction (LC) techniques to enhance construction management practices specifically for marble floor finishing work within Vietnam. Therefore, this study aims to apply the construction lean principle combined with discrete-event simulation (DES) by using EZStrobe to simulate the marble floor finishing process in reality, from observing and collecting data of each activity in the actual process on the site.

Facile Synthesis of Platinum Nanoparticle-Embedded Reduced Graphene Oxide for the Detection of Carbendazim.

In recent years, there has been a significant interest in the advancement of electrochemical sensing platforms to detect pesticides with high sensitivity and selectivity. Current research presents a novel approach utilising platinum nanoparticles (NPs) and reduced graphene oxide deposited on a glassy carbon electrode (Pt-rGO/GCE) for direct electrochemical measurement of carbendazim (CBZ). A straightforward one-step electrodeposition process was applied to prepare the Pt-rGO sensing platform.

A highly sensitive fluorescence nanosensor for determination of amikacin antibiotics using composites of carbon quantum dots and gold nanoparticles.

Amikacin is an aminoglycoside antibiotic widely used to treat various bacterial infections in humans. However, elevated concentrations of amikacin can damage the cochlear nerve. Thus, accurate and rapid amikacin detection is crucial.

Significance of MOF adsorbents in uranium remediation from water.

Uranium is considered as one of the most perilous radioactive contaminants in the aqueous environment. It has shown detrimental effects on both flora and fauna and because of its toxicities on human beings, therefore its exclusion from the aqueous environment is very essential. The utilization of metal-organic frameworks (MOFs) as an adsorbent for the removal of uranium from the aqueous environment could be a good approach.

Effectiveness of Opioid Switching in Advanced Cancer Pain: A Prospective Observational Cohort Study.

Opioid switching is a common practice of substituting one opioid for another to improve analgesia or adverse effects; however, it has limited evidence. This study aimed to examine the effectiveness of opioid switching in advanced cancer. This multi-center prospective cohort study recruited patients assessed to switch opioids (opioid switch group) or to continue ongoing opioid treatment (control group).

Removal of Acid Orange G Azo Dye by Polycation-Modified Alpha Alumina Nanoparticles.

Highly positively charged poly(vinyl benzyl trimethylammonium chloride) (PVBMA) was successfully synthesized with approximately 82% of yield. The PVBMA was characterized by the molecular weight (M ) of 343.45 g mol and the molecular weight distribution, (Đ) of 2.

Reactions of Methyl Radicals with Aniline Acting as Hydrogen Donors and as Methyl Radical Acceptors.

The present investigation theoretically reports the comprehensive kinetic mechanism of the reaction between aniline and the methyl radical over a wide range of temperatures (300-2000 K) and pressures (76-76,000 Torr). The potential energy surface of the CHNH + CH reaction has been established at the CCSD(T)//M06-2X/6-311++G(3df,2p) level of theory. The conventional transition-state theory (TST) was utilized to calculate rate constants for the elementary reaction channels, while the stochastic RRKM-based master equation framework was applied for the - and -dependent rate-coefficient calculation of multiwell reaction paths.

Mechanistic and Kinetic Approach on the Propargyl Radical (CH) with the Criegee Intermediate (CHOO).

The detailed reaction mechanism and kinetics of the CH + CHOO system have been thoroughly investigated. The CBS-QB3 method in conjunction with the ME/vRRKM theory has been applied to figure out the potential energy surface and rate constants for the CH + CHOO system. The CH + CHOO reaction leading to the CH-[cyc-CCHCHOO] + H product dominates compared to the others.

Natural Cellulose Fiber-Derived Photothermal Aerogel for Efficient and Sustainable Solar Desalination.

Aerogels are becoming a promising platform to fabricate photothermal materials for use in solar steam generation (SSG), which have remarkable application potential in solar desalination, due to their excellent thermal management, salt resistance, and considerable water evaporation rate. In this work, a novel photothermal material is fabricated by forming a suspension between sugarcane bagasse fibers (SBF) and poly(vinyl alcohol), tannic acid (TA), and Fe solutions via hydrogen bonds of hydroxyl groups. After freeze drying, the fabricated SBF aerogel-based photothermal (SBFAP) material possesses a 3D interconnected porous microstructure, which could enhance water transportation ability, reduce thermal conductivity, and quickly dissolve salt crystals on the SBFAP surface.

The use of mobile apps and fitness trackers to promote healthy behaviors during COVID-19: A cross-sectional survey.

Objectives: To examine i) the use of mobile apps and fitness trackers in adults during the COVID-19 pandemic to support health behaviors; ii) the use of COVID-19 apps; iii) associations between using mobile apps and fitness trackers, and health behaviors; iv) differences in usage amongst population subgroups.

Methods: An online cross-sectional survey was conducted during June-September 2020. The survey was developed and reviewed independently by co-authors to establish face validity.

Adsorptive removal of dichlorophenoxyacetic acid (2,4-D) using novel nanoparticles based on cationic surfactant-coated titania nanoparticles.

A novel nanomaterial based on cationic surfactant-coated TiO nanoparticle (CCTN) was systematically fabricated in this work. Synthesized titania nanoparticles were thoroughly characterized by XRD, FT-IR, HR-TEM, TEM-EDX, SEM with EDX mapping, BET, and ζ potential measurements. The adsorption of cationic surfactant, cetyltrimethylammonium bromide (CTAB), on TiO was studied under various pH and ionic strength conditions.

Nurses' perceptions about patient safety culture in public hospital in Vietnam.

Aim: This paper is aimed to assess nurses' perceptions of patient safety culture in four public general hospitals in Hanoi, Vietnam.

Background: Patient safety culture is a vital component in ensuring high quality and safe patient care. Assessment of nurses' perceptions on existing hospital patient safety culture (PSC) is the first step to promote PSC.

Patient Satisfaction With Healthcare Service Quality and Its Associated Factors at One Polyclinic in Hanoi, Vietnam.

: Patient satisfaction is one of the most important components of measuring healthcare quality. : The study aimed to evaluate the validity and reliability of the patient satisfaction scale with the quality of health services and its associated factors. A cross-sectional study was conducted to collect data on patient satisfaction with 301 outpatients at one polyclinic in Hanoi, Vietnam.

COVID-19 vaccine acceptance and its determinants among Vietnamese teachers: a web-based cross-sectional survey.

Objectives: This paper aimed to describe acceptance of the COVID-19 vaccine and its determinants among Vietnamese teachers.

Methods: This was a web-based cross-sectional survey with a sample of 17,176 teachers from kindergarten to high school who currently reside in Vietnam. A participant who exhibited "acceptance" towards the vaccine gave the following response: .

Adsorption and transformation of tetracyclines on alpha alumina particles with surface modification by anionic surfactant.

The adsorption and transformation of tetracyclines (TCs) antibiotics, including oxytetracycline (OTC), chlortetracycline (CTC), and tetracycline (TC), on the sodium dodecyl sulfate (SDS) surfactant-modified α-AlO particles were comprehensively investigated in this study. The TCs adsorption was significantly enhanced by using the modified adsorbents compared with the use of the unmodified adsorbents. The experimental conditions were systematically optimized and found to be pH 4, NaCl 1 mM, the contact time of 180 min, and the adsorbent dosage of 25 mg.