Mueller Matrix Polarimetry on Cyanine Dye -Aggregates.

Cyanine dyes are known to form - and -aggregates in aqueous solutions. Here we show that the cyanine dye, S0271, assembles in water into vortex induced chiral -aggregates. The chirality of the -aggregates depends on the directionality of the vortex.

Discovery of an all-donor aromatic [2]catenane.

We report herein the first all-donor aromatic [2]catenane formed through dynamic combinatorial chemistry, using single component libraries. The building block is a benzo[1,2-:4,5-']dithiophene derivative, a π-donor molecule, with cysteine appendages that allow for disulfide exchange. The hydrophobic effect plays an essential role in the formation of the all-donor [2]catenane.

Mapping the Chiroptical Properties of Local Domains in Thin Films of Chiral Silicon Phthalocyanines by CD Imaging.

The first example of uniformly chiral thin films of silicon phthalocyanines (SiPcs) are reported. The local domains of the films are mapped using circular dichroism (CD) imaging (CD) technique available at the Diamond B23 beamline. The CD allowed us to increase the spatial resolution up to 525× when compared with benchtop spectrometers.

Structurally divergent dynamic combinatorial chemistry on racemic mixtures.

Structurally Divergent Reactions on Racemic Mixtures are atypical processes in Nature. The few examples reported in the literature take place in organic solvents and are driven by the reagents' interaction with bulky chiral catalysts. Herein, we describe a dynamic combinatorial approach to generate structural divergence from racemic building blocks.

Chiral Phthalocyanines through Axial Coordination.

A novel approach to axially induce chirality on silicon phthalocyanines via a microwave-assisted route is reported. CD analysis provides spectroscopic evidence that chirality is transferred onto both Soret and Q-bands of the phthalocyanine core. A chiral naphthalenediimide ligand was found to induce the largest Cotton effect on the macrocycle absorptions.