Environmental behavior and risk of the emerging organic contaminants halogenated carbazoles in chemical industrial park clusters.

Polyhalogenated carbazoles (PHCZs) are emerging organic contaminants and have attracted extensive concern because of their widespread occurrence and dioxin-like toxicity. However, the distribution characteristics, environmental behavior, and fate of PHCZs are still poorly understood. In this study, 74 composite environmental samples from 21 Chinese cities were collected around industrial parks in the Yangtze River Delta.

p-Phenylenediamines and p-phenylenediamine quinone derivatives in rubber consumer products and typical urban dust: Sources, transformation profiles, and health risks.

N,N'-Substituted p-phenylenediamines (PPDs) are widely used as antioxidants in the rubber industry and are released into the environment in large quantities during the production and use of rubber products. We quantified PPDs and PPD quinone derivatives (PPD-Qs) in rubber consumer products, including car tires, rubber belts, rubber gloves, rubber cables, and rubber hoses, to obtain information on the degree of weathering over time during their use. Additionally, we investigated the occurrences and sources of PPDs and PPD-Qs in dust samples collected from four typical urban environments (roads, parking lots, automotive repair shops, and residences).

Distributions and transformation of polyhalogenated carbazoles in environmental matrices contaminated by printing and dyeing plants.

As emerging organic contaminants, Polyhalogenated carbazoles (PHCZs) have caused wide concerns due to their wide distribution in the environment and dioxin-like toxicity. Nevertheless, research on the distribution and formation mechanisms of PHCZs in polluted environment of printing and dyeing plants is lacking. Here, 11 PHCZs were detected in samples from the Cao'e River, China, a typical river heavily polluted by printing and dyeing.

Spatial distributions, behaviors, and sources of PCDD/Fs in surface water and sediment from the Yangtze River Delta.

The Yangtze River Delta (YRD), one of the most economically developed and industrialized regions in China, is confronted with challenges arising from rapid urbanization, particularly environmental pollution. The collection of surface water and sediment samples from forty-nine sites in the YRD was conducted to analyze 2378-substituted polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs) congeners. The detected concentrations of PCDD/Fs were 0-5.

A Review of Distribution and Profiles of HBCD in Different Environmental Media of China.

Hexabromocyclododecane (HBCD) is the most important flame retardant that has been used in Expanded Polystyrene foam and Extruded Polystyrene foam in the past forty years across the world. China was the major producer and user of HBCD, and the total HBCD production was about 0.3 million tons.

Occurrence and Formation Mechanism of PCDD/Fs and SCCPs in Chlorinated Paraffin Products.

Polychlorinated dibenzo--dioxins and dibenzofurans (PCDD/Fs) and short-chain chlorinated paraffins (SCCPs) can be formed during the production of chlorinated paraffins (CPs). Detection and accurate quantification of PCDD/Fs in CPs are challenging because of their matrix complexity. Therefore, the occurrence and formation mechanisms of PCDD/Fs from CPs have not been studied extensively in the past.

Weakly solvated EC-free linear alkyl carbonate electrolytes for Ni-rich cathode in rechargeable lithium battery.

Ethylene carbonate (EC) in the electrolyte is not stable in cells operated at high voltage (≥4.4V) or with Li metal anode, which greatly reduce the energy density and lifetime of the rechargeable lithium battery. Herein, an EC-free linear alkyl carbonate-based electrolyte is developed, which enables the high-voltage (≥4.

AGO4 suppresses tumor growth by modulating autophagy and apoptosis via enhancing TRIM21-mediated ubiquitination of GRP78 in a p53-independent manner.

Argonaute proteins, which consist of AGO1, AGO2, AGO3 and AGO4, are key players in microRNA-mediated gene silencing. So far, few non-microRNA related biological roles of AGO4 have been reported. Here, we first found that AGO4 had low expression in non-small cell lung cancer (NSCLC) patient tumor tissues and could suppress NSCLC cell proliferation and metastasis.

Facile Electroless Plating Method to Fabricate a Nickel-Phosphorus-Modified Copper Current Collector for a Lean Lithium-Metal Anode.

The compatibility of current collectors with reactive Li is key to inducing stable Li cycling and prolonged cycle life of lean Li-metal batteries. Herein, a thin and uniform layer of Ni-P complex was built on the surface of a Cu current collector (NiP@Cu) via an efficient, controllable, and cost-effective electroless plating method. The thickness, morphology, composition, and roughness of the Ni-P deposition were successfully regulated.

Rational Engineering of Anode Current Collector for Dendrite-Free Lithium Deposition: Strategy, Application, and Perspective.

Lithium metal anodes have attracted extensive attention due to their high theoretical capacity and low redox potential. However, low Coulombic efficiency, serious parasitic reaction, large volume change, and dendrite growth during cycling have hindered their practical application. The engineering of an anode current collector provides important advances to solve these problems, eliminate excess lithium usage, and substantially increase the energy density.

Perylene diimide growth on both sides of carbon nanotubes for remarkably boosted photocatalytic degradation of diclofenac.

Perylene diimide and its derivatives are promising photocatalysts for clean and efficient production, but their practical application in the field of photocatalysis is still limited by the rapid photogenerated charge recombination. In this work, the confined photocatalysts were synthesized by using a gas-phase self-assembly method and comparing the morphology and photocatalytic properties of different photocatalysts after the confinement of carbon nanotubes. The confinement effect of carbon nanotubes acts to stabilize perylene diimide.

Determination of Hexabromocyclododecane in Expanded Polystyrene and Extruded Polystyrene Foam by Gas Chromatography-Mass Spectrometry.

A gas chromatography-mass spectrometry (GC/MS) method for the determination of hexabromocyclododecane (HBCD) in expanded polystyrene and extruded polystyrene foam (EPS/XPS) was developed. The EPS/XPS samples were ultrasonically extracted with acetone and the extracts were purified by filtration through a microporous membrane (0.22 μm) and solid-phase extraction.

Investigation on Distribution and Risk Assessment of Volatile Organic Compounds in Surface Water, Sediment, and Soil in a Chemical Industrial Park and Adjacent Area.

The occurrences, distributions, and risks of 55 target volatile organic compounds (VOCs) in water, sediment, sludge, and soil samples taken from a chemical industrial park and the adjacent area were investigated in this study. The Σ-VOCs concentrations in the water, sediment, sludge, and soil samples were 1.22-5449.

Partitioning and potential sources of polychlorinated naphthalenes in water-sediment system from the Yangtze River Delta, China.

Spatial trends, partitioning behavior, and potential sources of polychlorinated naphthalenes (PCNs) in water-sediment system from the Yangtze River Delta (YRD) were investigated in this study. The total concentrations of 75 PCNs in water and sediment samples were 0.022-0.

Distributions of Polychlorinated Naphthalenes in Sediments of the Yangtze River, China.

The pollution status of polychlorinated naphthalenes (PCNs) in the sediment of the Yangtze River Basin, Asia's largest river basin, was estimated. The total concentrations of PCNs (mono- to octa-CNs) ranged from 0.103 to 1.

Global status of dioxin emission and China's role in reducing the emission.

The global status of dioxin emissions across 150 countries/regions were compiled in this study. China, the major emitter of dioxin and the largest developing country, was chosen as an example to illustrate its emission reductions. The global dioxin emissions were about 97.

Spatial distributions and sources of PAHs in soil in chemical industry parks in the Yangtze River Delta, China.

The Yangtze River Delta (YRD) is one of the fastest developing areas in eastern China and contains many chemical industry parks. The profiles and sources of polycyclic aromatic hydrocarbons (PAHs) in soil in chemical industry parks and surrounding areas in the YRD were investigated by analyzing soil samples (n = 64) were collected in the YRD and Rudong chemical park (RD), a typical chemical park in the Yangtze River Delta. The total concentrations of 19 PAHs in the YRD soil samples were 16.

Effects of air pollution control devices on volatile organic compounds reduction in coal-fired power plants.

Air pollution control devices (APCDs) have been fitted to many coal-fired power plants to decrease the impacts of pollutants generated during coal combustion. APCDs remove conventional pollutants but also decrease volatile organic compound (VOC) emissions. In this study, flue gas samples were collected from different points in seven typical coal-fired power and two industrial boilers, and the VOC concentrations in the flue gas samples were determined by gas chromatography-mass spectrometry (GC-MS).

DnaJ Proteins Regulate Expression in Shoot Apical Meristem of Arabidopsis.

WUSCHEL (WUS) protein regulates stem cell function in shoot apical meristem of . The expression of gene is strictly regulated by developmental cues and environmental factors. As DnaJ domain-containing proteins, SDJ1 and SDJ3 have been proven to play an important role in transcriptional activation of promoter methylated genes.

Coordinated effects of air pollution control devices on PAH emissions in coal-fired power plants and industrial boilers.

Coal-fired power plants are important sources of polycyclic aromatic hydrocarbon (PAH) emissions in the world. The effects of various air pollution control devices (APCDs) on PAH emissions were investigated by analyzing samples from inlets and outlets of APCDs in six coal-fired power plants (A-F) and two coal-fired industrial boilers (G and H). The APCDs were electrostatic precipitators (ESPs), wet flue gas desulfurization systems (WFGDs), and wet ESPs (WESPs).

Fabrication of nano/microstructures for SERS substrates using an electrochemical method.

Based on an electrochemical method, three-dimensional arrayed nanopore structures are machined onto a Mg surface. The structured Mg surface is coated with a thin gold (Au) film, which is used as a surface-enhanced Raman scattering (SERS) substrate. A rhodamine 6G (R6G) probe molecule is used as the detection agent for the SERS measurement.

The AtMYB2 inhibits the formation of axillary meristem in Arabidopsis by repressing RAX1 gene under environmental stresses.

AtMYB2 protein represses the formation of axillary meristems in response to environmental stresses so that plants can undergo a shorter vegetative development stage under environmental stresses. Shoot branching is an important event determined by endogenous factors during the development of plants. The formation of axillary meristem is also significantly repressed by environmental stresses and the underlying mechanism is largely unknown.