The β-relaxation is one of the major dynamic behaviors in metallic glasses (MGs) and exhibits diverse features. Despite decades of efforts, the understanding of its structural origin and contribution to the overall dynamics of MG systems is still unclear. Here two palladium-based Pd─Cu─P and Pd─Ni─P MGs are reported with distinct different β-relaxation behaviors and reveal the structural origins for the difference using the advanced X-ray photon correlation spectroscopy and absorption fine structure techniques together with the first-principles calculations.
View Article and Find Full Text PDFAmorphous alloys (AAs) are promising materials due to their unique properties and have been applied in various biomaterial coatings and micro-electro-mechanical systems. However, they have seldom been applied in the optical nano-device. Here, we systematically investigate morphology, microstructure, mechanical and optical properties of an Au-Cu-Si AA and successfully design and fabricate a broadband optical absorber using the Au-Cu-Si AA.
View Article and Find Full Text PDFWe use the pulse current thermoplastic forming technique based on joule heating to rejuvenate the atomic structure of a LaAlAgNiCo bulk metallic glass (BMG). The pulse-formed sample exhibits more pronounced β-relaxation than the as-cast one due to the increased free volume. Instead, the sub- annealing clearly weakens the β-relaxation and also makes it more isolated from the α-relaxation, showing contributions from free volume and preferred structure.
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