Unstable cathode/electrolyte interphase and severe interfacial side reaction have long been identified as the main cause for the failure of layered oxide cathode during fast charging and long-term cycling for rechargeable sodium-ion batteries. Here, we report a superionic conductor (NaV(PO), NVP) bonding surface strategy for O3-type layered NaNiFeMnO (NFM) cathode to suppress electrolyte corrosion and near-surface structure deconstruction, especially at high operating potential. The strong bonding affinity at the NVP/NFM contact interface stabilizes the crystal structure by inhibiting surface parasitic reactions and transition metal dissolution, thus significantly improving the phase change reversibility at high desodiation state and prolonging the lifespan of NFM cathode.
View Article and Find Full Text PDFGreen organic materials composed of C, H, O, and N elements are receiving more and more attention worldwide. However, the high solubility, poor electrical conductivity, and long activation time limit the development of organic materials in practice. Herein, two stable covalent organic materials with alkynyl linkage between benzene rings and benzothiadiazole groups with different amounts of fluorine atoms modification (defined as BOP-0F and BOP-2F), are designed for lithium-ion batteries.
View Article and Find Full Text PDFIron sulfides are widely explored as anodes of sodium-ion batteries (SIBs) owing to high theoretical capacities and low cost, but their practical application is still impeded by poor rate capability and fast capacity decay. Herein, for the first time, we construct highly dispersed FeS nanoparticles anchored on a porous N-doped carbon nanosheet (CN) skeleton (denoted as FeS/NC) with high conductivity and numerous active sites facile ion adsorption and thermal evaporation combined procedures coupled with a gas sulfurization treatment. Nanoscale design coupled with a conductive carbon skeleton can simultaneously mitigate the above obstacles to obtain enhanced structural stability and faster electrode reaction kinetics.
View Article and Find Full Text PDFOn account of the high theoretical capacity and preferable electrochemical reversibility, tin selenides have emerged as potential anode materials in the field of sodium ion batteries (SIBs). Unfortunately, the large volume changes, low electrical conductivity, and shuttling effect of polyselenides have impeded their real application. In this work, we present a spatially confined reaction approach for controllable fabrication of SnSe spheres, which are embedded in polydopamine (PDA)-derived N, Se dual-doped carbon networks (SnSe@NSC) through a one-step carbonization and selenization method.
View Article and Find Full Text PDFA facile method is adopted to obtain cucumber-like lithiophilic composite skeleton. Massive lithiophilic sites in cucumber-like lithiophilic composite skeleton can promote and guide uniform Li depositions. A unique model of stepwise Li deposition and stripping is determined.
View Article and Find Full Text PDF