Publications by authors named "Tian-Yu Pan"
Three new group IIIA metal phosphate-oxalate (MPO) compounds, namely [(CH)NH][M(HPO)(HPO)(CO)] (M = Al (1), Ga (2)) and [(CH)NH][In(HPO)(HPO)(CO)]·HO (3), have been synthesized. Their crystal structures feature an anionic layer with the topology net. In particular, 1 displays a proton conductivity () of 9.
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- - Two new cluster-based compounds with a one-dimensional belt-like structure were synthesized using solvothermal methods, featuring mixed-valence antimony (Sb(III,V)) in their compositions.
- - The structures are characterized by anionic clusters arranged in a sandwich formation, involving layers of specific chemical brackets and components related to cobalt and tartaric acid.
- - The second compound was found to have significant proton conductivity, reaching 1.42 × 10⁻² S/cm at 85 °C under high humidity conditions, demonstrating its potential for applications in conductive materials.
Unveiling the structural evolution of single-crystalline compounds based on certain building units may help greatly in guiding the design of complex structures. Herein, a series of praseodymium antimony oxohalide crystals have been isolated under solvothermal conditions via adjusting the solvents used, that is, [HN(CHCH)][Fe(2,2'-bpy)][PrSbOCl]·EtOH () (2,2'-bpy = 2,2'-bipyridine), [HN(CHCH)][Fe(2,2'-bpy)][PrSbOCl)Cl]·N(CHCH)·2HO (), and (HO)[PrSbOCl(TEOA)]·2.5EtOH () (TEOA = mono-deprotonated triethanolamine anion).
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