Single-molecule imaging of activated nitrogen adsorption on individual manganese phthalocyanine.

An atomic-scale understanding of gas adsorption mechanisms on metal-porphyrins or metal-phthalocyanines is essential for their practical application in biological processes, gas sensing, and catalysis. Intensive research efforts have been devoted to the study of coordinative bonding with relatively active small molecules such as CO, NO, NH3, O2, and H2. However, the binding of single nitrogen atoms has never been addressed, which is both of fundamental interest and indeed essential for revealing the elementary chemical binding mechanism in nitrogen reduction processes.

Rational design of two-dimensional molecular donor-acceptor nanostructure arrays.

The construction of long-range ordered organic donor-acceptor nanostructure arrays over microscopic areas supported on solid substrates is one of the most challenging tasks towards the realization of molecular nanodevices. They can also be used as ideal model systems to understand light induced charge transfer, charge separation and energy conversion processes and mechanisms at the nanometer scale. The aim of this paper is to highlight recent advances and progress in this topic.

Self-assembly of binary molecular nanostructure arrays on graphite.

The controlled positioning and assembly of functional molecules into ordered nanostructures on surfaces depends on the interplay of multiple interactions on different strength and length scales. On metal surfaces, the relatively strong molecule-substrate interactions can constrain the molecules to adsorb in registry with the surface periodicity and lock them into specific adsorption sites. This can significantly reduce the structural tunability of the molecular nanostructure arrays formed.

Reversible single-molecule switching in an ordered monolayer molecular dipole array.

Making electronic devices using a single molecule has been the ultimate goal of molecular electronics. For binary data storage in particular, the challenge has been the ability to switch a single molecule in between bistable states in a simple and repeatable manner. The reversible switching of single molecules of chloroaluminum phthalocyanine (ClAlPc) dipolar molecules within a close-packed monolayer is demonstrated.

One dimensional molecular dipole chain arrays on graphite via nanoscale phase separation.

Molecular dipole chain arrays of chloroaluminium phthalocyanine (ClAlPc) on the graphite surface have been investigated by scanning tunneling microscopy. The inter-chain spacing can be tuned by the co-adsorption of di-indenoperylene (DIP) via nanoscale phase separation.